Aqua­[tris­(2-{5-[(4-methyl­phenyl)diazen­yl]-2-oxidobenzyl­idene­amino}­eth­yl)amine]­samarium(III) acetonitrile monosolvate

In the title compound, [Sm(C(48)H(45)N(10)O(3))(H(2)O)]·CH(3)CN, the Sm(III) ion is coordinated by the hepta­dentate tris­(2-{5-[(4-methyl­pheny)diazen­yl]-2-oxidobenzyl­idene­amino}­eth­yl)amine trianionic ligand and a water mol­ecule. The resulting SmN(4)O(4) coordination polyhedron is a distorted...

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Detalles Bibliográficos
Autores principales: Salehzadeh, Sadegh, Mahdavian, Mahsa, Khalaj, Mehdi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274845/
https://www.ncbi.nlm.nih.gov/pubmed/22346894
http://dx.doi.org/10.1107/S1600536811054961
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author Salehzadeh, Sadegh
Mahdavian, Mahsa
Khalaj, Mehdi
author_facet Salehzadeh, Sadegh
Mahdavian, Mahsa
Khalaj, Mehdi
author_sort Salehzadeh, Sadegh
collection PubMed
description In the title compound, [Sm(C(48)H(45)N(10)O(3))(H(2)O)]·CH(3)CN, the Sm(III) ion is coordinated by the hepta­dentate tris­(2-{5-[(4-methyl­pheny)diazen­yl]-2-oxidobenzyl­idene­amino}­eth­yl)amine trianionic ligand and a water mol­ecule. The resulting SmN(4)O(4) coordination polyhedron is a distorted square anti­prism. In the crystal, complex mol­ecules are linked by O—H⋯O hydrogen bonds.
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spelling pubmed-32748452012-02-15 Aqua­[tris­(2-{5-[(4-methyl­phenyl)diazen­yl]-2-oxidobenzyl­idene­amino}­eth­yl)amine]­samarium(III) acetonitrile monosolvate Salehzadeh, Sadegh Mahdavian, Mahsa Khalaj, Mehdi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sm(C(48)H(45)N(10)O(3))(H(2)O)]·CH(3)CN, the Sm(III) ion is coordinated by the hepta­dentate tris­(2-{5-[(4-methyl­pheny)diazen­yl]-2-oxidobenzyl­idene­amino}­eth­yl)amine trianionic ligand and a water mol­ecule. The resulting SmN(4)O(4) coordination polyhedron is a distorted square anti­prism. In the crystal, complex mol­ecules are linked by O—H⋯O hydrogen bonds. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3274845/ /pubmed/22346894 http://dx.doi.org/10.1107/S1600536811054961 Text en © Salehzadeh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Salehzadeh, Sadegh
Mahdavian, Mahsa
Khalaj, Mehdi
Aqua­[tris­(2-{5-[(4-methyl­phenyl)diazen­yl]-2-oxidobenzyl­idene­amino}­eth­yl)amine]­samarium(III) acetonitrile monosolvate
title Aqua­[tris­(2-{5-[(4-methyl­phenyl)diazen­yl]-2-oxidobenzyl­idene­amino}­eth­yl)amine]­samarium(III) acetonitrile monosolvate
title_full Aqua­[tris­(2-{5-[(4-methyl­phenyl)diazen­yl]-2-oxidobenzyl­idene­amino}­eth­yl)amine]­samarium(III) acetonitrile monosolvate
title_fullStr Aqua­[tris­(2-{5-[(4-methyl­phenyl)diazen­yl]-2-oxidobenzyl­idene­amino}­eth­yl)amine]­samarium(III) acetonitrile monosolvate
title_full_unstemmed Aqua­[tris­(2-{5-[(4-methyl­phenyl)diazen­yl]-2-oxidobenzyl­idene­amino}­eth­yl)amine]­samarium(III) acetonitrile monosolvate
title_short Aqua­[tris­(2-{5-[(4-methyl­phenyl)diazen­yl]-2-oxidobenzyl­idene­amino}­eth­yl)amine]­samarium(III) acetonitrile monosolvate
title_sort aqua­[tris­(2-{5-[(4-methyl­phenyl)diazen­yl]-2-oxidobenzyl­idene­amino}­eth­yl)amine]­samarium(iii) acetonitrile monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274845/
https://www.ncbi.nlm.nih.gov/pubmed/22346894
http://dx.doi.org/10.1107/S1600536811054961
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AT khalajmehdi aquatris254methylphenyldiazenyl2oxidobenzylideneaminoethylaminesamariumiiiacetonitrilemonosolvate

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