Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate
In the title compound, [Sm(C(48)H(45)N(10)O(3))(H(2)O)]·CH(3)CN, the Sm(III) ion is coordinated by the heptadentate tris(2-{5-[(4-methylpheny)diazenyl]-2-oxidobenzylideneamino}ethyl)amine trianionic ligand and a water molecule. The resulting SmN(4)O(4) coordination polyhedron is a distorted...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274845/ https://www.ncbi.nlm.nih.gov/pubmed/22346894 http://dx.doi.org/10.1107/S1600536811054961 |
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author | Salehzadeh, Sadegh Mahdavian, Mahsa Khalaj, Mehdi |
author_facet | Salehzadeh, Sadegh Mahdavian, Mahsa Khalaj, Mehdi |
author_sort | Salehzadeh, Sadegh |
collection | PubMed |
description | In the title compound, [Sm(C(48)H(45)N(10)O(3))(H(2)O)]·CH(3)CN, the Sm(III) ion is coordinated by the heptadentate tris(2-{5-[(4-methylpheny)diazenyl]-2-oxidobenzylideneamino}ethyl)amine trianionic ligand and a water molecule. The resulting SmN(4)O(4) coordination polyhedron is a distorted square antiprism. In the crystal, complex molecules are linked by O—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3274845 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32748452012-02-15 Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate Salehzadeh, Sadegh Mahdavian, Mahsa Khalaj, Mehdi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sm(C(48)H(45)N(10)O(3))(H(2)O)]·CH(3)CN, the Sm(III) ion is coordinated by the heptadentate tris(2-{5-[(4-methylpheny)diazenyl]-2-oxidobenzylideneamino}ethyl)amine trianionic ligand and a water molecule. The resulting SmN(4)O(4) coordination polyhedron is a distorted square antiprism. In the crystal, complex molecules are linked by O—H⋯O hydrogen bonds. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3274845/ /pubmed/22346894 http://dx.doi.org/10.1107/S1600536811054961 Text en © Salehzadeh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Salehzadeh, Sadegh Mahdavian, Mahsa Khalaj, Mehdi Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate |
title | Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate |
title_full | Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate |
title_fullStr | Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate |
title_full_unstemmed | Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate |
title_short | Aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III) acetonitrile monosolvate |
title_sort | aqua[tris(2-{5-[(4-methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(iii) acetonitrile monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274845/ https://www.ncbi.nlm.nih.gov/pubmed/22346894 http://dx.doi.org/10.1107/S1600536811054961 |
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