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Poly[(μ(4)-3-carboxybenzoato-κ(5) O (1):O (1),O (1′):O (1′):O (3))(quinolin-8-olato-κ(2) N,O)lead(II)]
The asymmetric unit of the title complex, [Pb(C(8)H(5)O(4))(C(9)H(6)NO)](n), comprises a Pb(II) cation, a quinolin-8-olate anion and a 3-carboxybenzoate anion. The coordination geometry of the Pb(II) atom is defined by one N and six O atoms, as well as a stereochemically active lone pair of electr...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274846/ https://www.ncbi.nlm.nih.gov/pubmed/22346895 http://dx.doi.org/10.1107/S160053681105495X |
Sumario: | The asymmetric unit of the title complex, [Pb(C(8)H(5)O(4))(C(9)H(6)NO)](n), comprises a Pb(II) cation, a quinolin-8-olate anion and a 3-carboxybenzoate anion. The coordination geometry of the Pb(II) atom is defined by one N and six O atoms, as well as a stereochemically active lone pair of electrons, and is based on a Ψ-dodecahedron. The quinolin-8-olate is chelating and the 3-carboxybenzoate anion forms bonds to four different Pb(II) atoms. The benzoate end of the 3-carboxybenzoate ligand chelates one Pb(II) atom and simultaneously bridges two Pb(II) atoms on either side, forming a chain along the b axis. The carboxyl end of the 3-carboxybenzoate connects to a neighbouring chain by employing its carbonyl atom to form a bond to a Pb(II) atom and the hydroxyl group to form a hydrogen bond to a quinolin-8-olate O atom. Thereby, a layer is formed in the bc plane. |
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