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Poly[(μ(4)-3-carboxybenzoato-κ(5) O (1):O (1),O (1′):O (1′):O (3))(quinolin-8-olato-κ(2) N,O)lead(II)]
The asymmetric unit of the title complex, [Pb(C(8)H(5)O(4))(C(9)H(6)NO)](n), comprises a Pb(II) cation, a quinolin-8-olate anion and a 3-carboxybenzoate anion. The coordination geometry of the Pb(II) atom is defined by one N and six O atoms, as well as a stereochemically active lone pair of electr...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274846/ https://www.ncbi.nlm.nih.gov/pubmed/22346895 http://dx.doi.org/10.1107/S160053681105495X |
| _version_ | 1782223118442430464 |
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| author | Ghaemi, Akbar Dadkhah, Zohreh Ng, Seik Weng Tiekink, Edward R. T. |
| author_facet | Ghaemi, Akbar Dadkhah, Zohreh Ng, Seik Weng Tiekink, Edward R. T. |
| author_sort | Ghaemi, Akbar |
| collection | PubMed |
| description | The asymmetric unit of the title complex, [Pb(C(8)H(5)O(4))(C(9)H(6)NO)](n), comprises a Pb(II) cation, a quinolin-8-olate anion and a 3-carboxybenzoate anion. The coordination geometry of the Pb(II) atom is defined by one N and six O atoms, as well as a stereochemically active lone pair of electrons, and is based on a Ψ-dodecahedron. The quinolin-8-olate is chelating and the 3-carboxybenzoate anion forms bonds to four different Pb(II) atoms. The benzoate end of the 3-carboxybenzoate ligand chelates one Pb(II) atom and simultaneously bridges two Pb(II) atoms on either side, forming a chain along the b axis. The carboxyl end of the 3-carboxybenzoate connects to a neighbouring chain by employing its carbonyl atom to form a bond to a Pb(II) atom and the hydroxyl group to form a hydrogen bond to a quinolin-8-olate O atom. Thereby, a layer is formed in the bc plane. |
| format | Online Article Text |
| id | pubmed-3274846 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32748462012-02-15 Poly[(μ(4)-3-carboxybenzoato-κ(5) O (1):O (1),O (1′):O (1′):O (3))(quinolin-8-olato-κ(2) N,O)lead(II)] Ghaemi, Akbar Dadkhah, Zohreh Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Pb(C(8)H(5)O(4))(C(9)H(6)NO)](n), comprises a Pb(II) cation, a quinolin-8-olate anion and a 3-carboxybenzoate anion. The coordination geometry of the Pb(II) atom is defined by one N and six O atoms, as well as a stereochemically active lone pair of electrons, and is based on a Ψ-dodecahedron. The quinolin-8-olate is chelating and the 3-carboxybenzoate anion forms bonds to four different Pb(II) atoms. The benzoate end of the 3-carboxybenzoate ligand chelates one Pb(II) atom and simultaneously bridges two Pb(II) atoms on either side, forming a chain along the b axis. The carboxyl end of the 3-carboxybenzoate connects to a neighbouring chain by employing its carbonyl atom to form a bond to a Pb(II) atom and the hydroxyl group to form a hydrogen bond to a quinolin-8-olate O atom. Thereby, a layer is formed in the bc plane. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3274846/ /pubmed/22346895 http://dx.doi.org/10.1107/S160053681105495X Text en © Ghaemi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ghaemi, Akbar Dadkhah, Zohreh Ng, Seik Weng Tiekink, Edward R. T. Poly[(μ(4)-3-carboxybenzoato-κ(5) O (1):O (1),O (1′):O (1′):O (3))(quinolin-8-olato-κ(2) N,O)lead(II)] |
| title | Poly[(μ(4)-3-carboxybenzoato-κ(5)
O
(1):O
(1),O
(1′):O
(1′):O
(3))(quinolin-8-olato-κ(2)
N,O)lead(II)] |
| title_full | Poly[(μ(4)-3-carboxybenzoato-κ(5)
O
(1):O
(1),O
(1′):O
(1′):O
(3))(quinolin-8-olato-κ(2)
N,O)lead(II)] |
| title_fullStr | Poly[(μ(4)-3-carboxybenzoato-κ(5)
O
(1):O
(1),O
(1′):O
(1′):O
(3))(quinolin-8-olato-κ(2)
N,O)lead(II)] |
| title_full_unstemmed | Poly[(μ(4)-3-carboxybenzoato-κ(5)
O
(1):O
(1),O
(1′):O
(1′):O
(3))(quinolin-8-olato-κ(2)
N,O)lead(II)] |
| title_short | Poly[(μ(4)-3-carboxybenzoato-κ(5)
O
(1):O
(1),O
(1′):O
(1′):O
(3))(quinolin-8-olato-κ(2)
N,O)lead(II)] |
| title_sort | poly[(μ(4)-3-carboxybenzoato-κ(5)
o
(1):o
(1),o
(1′):o
(1′):o
(3))(quinolin-8-olato-κ(2)
n,o)lead(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274846/ https://www.ncbi.nlm.nih.gov/pubmed/22346895 http://dx.doi.org/10.1107/S160053681105495X |
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