Poly[(μ(4)-5-bromo­pyridine-3-sulfonato)­silver(I)]

The silver(I) complex, [Ag(C(5)H(3)BrNO(3)S)](n), was obtained by reaction of AgNO(3) and 5-bromopyridine-3-sulfonic acid. The Ag(I) ion is coordinated by an O(3)N donor set in a slightly distorted tetra­hedral geometry. The Ag(I) ions are linked by μ(4)-5-bromo­pyridine-3-sulfonate ligands, forming...

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Detalles Bibliográficos
Autores principales: Lu, Ying-Bing, Jian, Fang-Mei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274848/
https://www.ncbi.nlm.nih.gov/pubmed/22346795
http://dx.doi.org/10.1107/S1600536811055206
Descripción
Sumario:The silver(I) complex, [Ag(C(5)H(3)BrNO(3)S)](n), was obtained by reaction of AgNO(3) and 5-bromopyridine-3-sulfonic acid. The Ag(I) ion is coordinated by an O(3)N donor set in a slightly distorted tetra­hedral geometry. The Ag(I) ions are linked by μ(4)-5-bromo­pyridine-3-sulfonate ligands, forming a layer parallel to (100). The layers are further connected via C—H⋯Br hydrogen-bonding inter­actions into a three-dimensional supra­molecular network. The Ag⋯Ag separation is 3.0159 (6) Å, indicating the presence of argentophilic inter­actions.

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