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Poly[(μ(4)-5-bromopyridine-3-sulfonato)silver(I)]
The silver(I) complex, [Ag(C(5)H(3)BrNO(3)S)](n), was obtained by reaction of AgNO(3) and 5-bromopyridine-3-sulfonic acid. The Ag(I) ion is coordinated by an O(3)N donor set in a slightly distorted tetrahedral geometry. The Ag(I) ions are linked by μ(4)-5-bromopyridine-3-sulfonate ligands, forming...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274848/ https://www.ncbi.nlm.nih.gov/pubmed/22346795 http://dx.doi.org/10.1107/S1600536811055206 |
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author | Lu, Ying-Bing Jian, Fang-Mei |
author_facet | Lu, Ying-Bing Jian, Fang-Mei |
author_sort | Lu, Ying-Bing |
collection | PubMed |
description | The silver(I) complex, [Ag(C(5)H(3)BrNO(3)S)](n), was obtained by reaction of AgNO(3) and 5-bromopyridine-3-sulfonic acid. The Ag(I) ion is coordinated by an O(3)N donor set in a slightly distorted tetrahedral geometry. The Ag(I) ions are linked by μ(4)-5-bromopyridine-3-sulfonate ligands, forming a layer parallel to (100). The layers are further connected via C—H⋯Br hydrogen-bonding interactions into a three-dimensional supramolecular network. The Ag⋯Ag separation is 3.0159 (6) Å, indicating the presence of argentophilic interactions. |
format | Online Article Text |
id | pubmed-3274848 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32748482012-02-15 Poly[(μ(4)-5-bromopyridine-3-sulfonato)silver(I)] Lu, Ying-Bing Jian, Fang-Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The silver(I) complex, [Ag(C(5)H(3)BrNO(3)S)](n), was obtained by reaction of AgNO(3) and 5-bromopyridine-3-sulfonic acid. The Ag(I) ion is coordinated by an O(3)N donor set in a slightly distorted tetrahedral geometry. The Ag(I) ions are linked by μ(4)-5-bromopyridine-3-sulfonate ligands, forming a layer parallel to (100). The layers are further connected via C—H⋯Br hydrogen-bonding interactions into a three-dimensional supramolecular network. The Ag⋯Ag separation is 3.0159 (6) Å, indicating the presence of argentophilic interactions. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3274848/ /pubmed/22346795 http://dx.doi.org/10.1107/S1600536811055206 Text en © Lu and Jian 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Lu, Ying-Bing Jian, Fang-Mei Poly[(μ(4)-5-bromopyridine-3-sulfonato)silver(I)] |
title | Poly[(μ(4)-5-bromopyridine-3-sulfonato)silver(I)] |
title_full | Poly[(μ(4)-5-bromopyridine-3-sulfonato)silver(I)] |
title_fullStr | Poly[(μ(4)-5-bromopyridine-3-sulfonato)silver(I)] |
title_full_unstemmed | Poly[(μ(4)-5-bromopyridine-3-sulfonato)silver(I)] |
title_short | Poly[(μ(4)-5-bromopyridine-3-sulfonato)silver(I)] |
title_sort | poly[(μ(4)-5-bromopyridine-3-sulfonato)silver(i)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274848/ https://www.ncbi.nlm.nih.gov/pubmed/22346795 http://dx.doi.org/10.1107/S1600536811055206 |
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