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Poly[(μ(4)-5-bromo­pyridine-3-sulfonato)­silver(I)]

The silver(I) complex, [Ag(C(5)H(3)BrNO(3)S)](n), was obtained by reaction of AgNO(3) and 5-bromopyridine-3-sulfonic acid. The Ag(I) ion is coordinated by an O(3)N donor set in a slightly distorted tetra­hedral geometry. The Ag(I) ions are linked by μ(4)-5-bromo­pyridine-3-sulfonate ligands, forming...

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Detalles Bibliográficos
Autores principales: Lu, Ying-Bing, Jian, Fang-Mei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274848/
https://www.ncbi.nlm.nih.gov/pubmed/22346795
http://dx.doi.org/10.1107/S1600536811055206
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author Lu, Ying-Bing
Jian, Fang-Mei
author_facet Lu, Ying-Bing
Jian, Fang-Mei
author_sort Lu, Ying-Bing
collection PubMed
description The silver(I) complex, [Ag(C(5)H(3)BrNO(3)S)](n), was obtained by reaction of AgNO(3) and 5-bromopyridine-3-sulfonic acid. The Ag(I) ion is coordinated by an O(3)N donor set in a slightly distorted tetra­hedral geometry. The Ag(I) ions are linked by μ(4)-5-bromo­pyridine-3-sulfonate ligands, forming a layer parallel to (100). The layers are further connected via C—H⋯Br hydrogen-bonding inter­actions into a three-dimensional supra­molecular network. The Ag⋯Ag separation is 3.0159 (6) Å, indicating the presence of argentophilic inter­actions.
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spelling pubmed-32748482012-02-15 Poly[(μ(4)-5-bromo­pyridine-3-sulfonato)­silver(I)] Lu, Ying-Bing Jian, Fang-Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The silver(I) complex, [Ag(C(5)H(3)BrNO(3)S)](n), was obtained by reaction of AgNO(3) and 5-bromopyridine-3-sulfonic acid. The Ag(I) ion is coordinated by an O(3)N donor set in a slightly distorted tetra­hedral geometry. The Ag(I) ions are linked by μ(4)-5-bromo­pyridine-3-sulfonate ligands, forming a layer parallel to (100). The layers are further connected via C—H⋯Br hydrogen-bonding inter­actions into a three-dimensional supra­molecular network. The Ag⋯Ag separation is 3.0159 (6) Å, indicating the presence of argentophilic inter­actions. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3274848/ /pubmed/22346795 http://dx.doi.org/10.1107/S1600536811055206 Text en © Lu and Jian 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lu, Ying-Bing
Jian, Fang-Mei
Poly[(μ(4)-5-bromo­pyridine-3-sulfonato)­silver(I)]
title Poly[(μ(4)-5-bromo­pyridine-3-sulfonato)­silver(I)]
title_full Poly[(μ(4)-5-bromo­pyridine-3-sulfonato)­silver(I)]
title_fullStr Poly[(μ(4)-5-bromo­pyridine-3-sulfonato)­silver(I)]
title_full_unstemmed Poly[(μ(4)-5-bromo­pyridine-3-sulfonato)­silver(I)]
title_short Poly[(μ(4)-5-bromo­pyridine-3-sulfonato)­silver(I)]
title_sort poly[(μ(4)-5-bromo­pyridine-3-sulfonato)­silver(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274848/
https://www.ncbi.nlm.nih.gov/pubmed/22346795
http://dx.doi.org/10.1107/S1600536811055206
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