trans-Diiodidobis(2-phenyl­pyridine-κN)palladium(II)

In the title complex, [PdI(2)(C(11)H(9)N)(2)], the Pd(II) ion has a distorted trans-I(2)N(2) square-planar coordination geometry defined by two N atoms from two 2-phenyl­pyridine ligands and two I(−) anions. The 2-phenyl­pyridine ligands are not planar, the dihedral angles between the pyridine and b...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274849/
https://www.ncbi.nlm.nih.gov/pubmed/22346796
http://dx.doi.org/10.1107/S1600536811055425
Descripción
Sumario:In the title complex, [PdI(2)(C(11)H(9)N)(2)], the Pd(II) ion has a distorted trans-I(2)N(2) square-planar coordination geometry defined by two N atoms from two 2-phenyl­pyridine ligands and two I(−) anions. The 2-phenyl­pyridine ligands are not planar, the dihedral angles between the pyridine and benzene rings being 50.1 (2) and 45.7 (2)°. An inter­molecular π–π inter­action between the six-membered rings is present, the ring centroid–centroid distance being 3.898 (4) Å.

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