Bis[μ-4-(2-oxidobenzyl­idene)thio­semi­carbazidato-κ(4) S,N (1),O:O]bis­[(pyridine-κN)zinc]

In the title compound, [Zn(2)(C(8)H(7)N(3)OS)(2)(C(5)H(5)N)(2)], the Zn(2)O(2) ring has a flattened roof shape, with the roof angle equal to 10.10 (6)°. The thio­semicarbazones act as tridentate ligands to one Zn(II) atom, with the O atoms additionally in bridging positions to the second Zn(II) atom...

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Detalles Bibliográficos
Autores principales: Takjoo, Reza, Dutkiewicz, Grzegorz, Ahmadi, Mehdi, Kubicki, Maciej
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274852/
https://www.ncbi.nlm.nih.gov/pubmed/22346799
http://dx.doi.org/10.1107/S160053681105522X
Descripción
Sumario:In the title compound, [Zn(2)(C(8)H(7)N(3)OS)(2)(C(5)H(5)N)(2)], the Zn(2)O(2) ring has a flattened roof shape, with the roof angle equal to 10.10 (6)°. The thio­semicarbazones act as tridentate ligands to one Zn(II) atom, with the O atoms additionally in bridging positions to the second Zn(II) atom. Both Zn(II) atoms are five-coordinated; the coordination polyhedra are close to square pyramids, with the pyridine N atoms at apical positions. Two inter­molecular N—H⋯N and one relatively weak N—H⋯S hydrogen bond, together with C—H⋯S weak inter­actions, connect the mol­ecules into a three-dimensional network.

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