Bis[μ-4-(2-oxidobenzyl­idene)thio­semi­carbazidato-κ(4) S,N (1),O:O]bis­[(pyridine-κN)zinc]

In the title compound, [Zn(2)(C(8)H(7)N(3)OS)(2)(C(5)H(5)N)(2)], the Zn(2)O(2) ring has a flattened roof shape, with the roof angle equal to 10.10 (6)°. The thio­semicarbazones act as tridentate ligands to one Zn(II) atom, with the O atoms additionally in bridging positions to the second Zn(II) atom...

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Autores principales: Takjoo, Reza, Dutkiewicz, Grzegorz, Ahmadi, Mehdi, Kubicki, Maciej
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274852/
https://www.ncbi.nlm.nih.gov/pubmed/22346799
http://dx.doi.org/10.1107/S160053681105522X
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author Takjoo, Reza
Dutkiewicz, Grzegorz
Ahmadi, Mehdi
Kubicki, Maciej
author_facet Takjoo, Reza
Dutkiewicz, Grzegorz
Ahmadi, Mehdi
Kubicki, Maciej
author_sort Takjoo, Reza
collection PubMed
description In the title compound, [Zn(2)(C(8)H(7)N(3)OS)(2)(C(5)H(5)N)(2)], the Zn(2)O(2) ring has a flattened roof shape, with the roof angle equal to 10.10 (6)°. The thio­semicarbazones act as tridentate ligands to one Zn(II) atom, with the O atoms additionally in bridging positions to the second Zn(II) atom. Both Zn(II) atoms are five-coordinated; the coordination polyhedra are close to square pyramids, with the pyridine N atoms at apical positions. Two inter­molecular N—H⋯N and one relatively weak N—H⋯S hydrogen bond, together with C—H⋯S weak inter­actions, connect the mol­ecules into a three-dimensional network.
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spelling pubmed-32748522012-02-15 Bis[μ-4-(2-oxidobenzyl­idene)thio­semi­carbazidato-κ(4) S,N (1),O:O]bis­[(pyridine-κN)zinc] Takjoo, Reza Dutkiewicz, Grzegorz Ahmadi, Mehdi Kubicki, Maciej Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(2)(C(8)H(7)N(3)OS)(2)(C(5)H(5)N)(2)], the Zn(2)O(2) ring has a flattened roof shape, with the roof angle equal to 10.10 (6)°. The thio­semicarbazones act as tridentate ligands to one Zn(II) atom, with the O atoms additionally in bridging positions to the second Zn(II) atom. Both Zn(II) atoms are five-coordinated; the coordination polyhedra are close to square pyramids, with the pyridine N atoms at apical positions. Two inter­molecular N—H⋯N and one relatively weak N—H⋯S hydrogen bond, together with C—H⋯S weak inter­actions, connect the mol­ecules into a three-dimensional network. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3274852/ /pubmed/22346799 http://dx.doi.org/10.1107/S160053681105522X Text en © Takjoo et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Takjoo, Reza
Dutkiewicz, Grzegorz
Ahmadi, Mehdi
Kubicki, Maciej
Bis[μ-4-(2-oxidobenzyl­idene)thio­semi­carbazidato-κ(4) S,N (1),O:O]bis­[(pyridine-κN)zinc]
title Bis[μ-4-(2-oxidobenzyl­idene)thio­semi­carbazidato-κ(4) S,N (1),O:O]bis­[(pyridine-κN)zinc]
title_full Bis[μ-4-(2-oxidobenzyl­idene)thio­semi­carbazidato-κ(4) S,N (1),O:O]bis­[(pyridine-κN)zinc]
title_fullStr Bis[μ-4-(2-oxidobenzyl­idene)thio­semi­carbazidato-κ(4) S,N (1),O:O]bis­[(pyridine-κN)zinc]
title_full_unstemmed Bis[μ-4-(2-oxidobenzyl­idene)thio­semi­carbazidato-κ(4) S,N (1),O:O]bis­[(pyridine-κN)zinc]
title_short Bis[μ-4-(2-oxidobenzyl­idene)thio­semi­carbazidato-κ(4) S,N (1),O:O]bis­[(pyridine-κN)zinc]
title_sort bis[μ-4-(2-oxidobenzyl­idene)thio­semi­carbazidato-κ(4) s,n (1),o:o]bis­[(pyridine-κn)zinc]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274852/
https://www.ncbi.nlm.nih.gov/pubmed/22346799
http://dx.doi.org/10.1107/S160053681105522X
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