Bis{2-[3-(hy­droxy­imino-κN)butan-2-yl­idene]-N-methyl­hydrazinecarbothio­amide-κ(2) N (2),S}nickel(II) dichloride

The asymmetric unit of the title compound, [Ni(C(6)H(12)N(4)OS)(2)]Cl(2), contains two independent Ni(II) complex cations and four chloride anions. Each Ni(II) ion is six-coordinated in a distorted octa­hedral geometry by four N atoms from the two imine and two oxime groups and two S atoms from the...

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Autores principales: Abduelftah, Halema Shaban, Qasem Ali, Amna, Eltayeb, Naser Eltaher, Teoh, Siang Guan, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274853/
https://www.ncbi.nlm.nih.gov/pubmed/22346800
http://dx.doi.org/10.1107/S1600536811055395
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author Abduelftah, Halema Shaban
Qasem Ali, Amna
Eltayeb, Naser Eltaher
Teoh, Siang Guan
Fun, Hoong-Kun
author_facet Abduelftah, Halema Shaban
Qasem Ali, Amna
Eltayeb, Naser Eltaher
Teoh, Siang Guan
Fun, Hoong-Kun
author_sort Abduelftah, Halema Shaban
collection PubMed
description The asymmetric unit of the title compound, [Ni(C(6)H(12)N(4)OS)(2)]Cl(2), contains two independent Ni(II) complex cations and four chloride anions. Each Ni(II) ion is six-coordinated in a distorted octa­hedral geometry by four N atoms from the two imine and two oxime groups and two S atoms from the thione group. In the crystal, the cations and anions are linked through N—H⋯Cl and O—H⋯Cl hydrogen bonds into infinite chains propagating along [10[Image: see text]]. Weak inter­molecular C—H⋯O and C—H⋯Cl hydrogen bonds are also observed.
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spelling pubmed-32748532012-02-15 Bis{2-[3-(hy­droxy­imino-κN)butan-2-yl­idene]-N-methyl­hydrazinecarbothio­amide-κ(2) N (2),S}nickel(II) dichloride Abduelftah, Halema Shaban Qasem Ali, Amna Eltayeb, Naser Eltaher Teoh, Siang Guan Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ni(C(6)H(12)N(4)OS)(2)]Cl(2), contains two independent Ni(II) complex cations and four chloride anions. Each Ni(II) ion is six-coordinated in a distorted octa­hedral geometry by four N atoms from the two imine and two oxime groups and two S atoms from the thione group. In the crystal, the cations and anions are linked through N—H⋯Cl and O—H⋯Cl hydrogen bonds into infinite chains propagating along [10[Image: see text]]. Weak inter­molecular C—H⋯O and C—H⋯Cl hydrogen bonds are also observed. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3274853/ /pubmed/22346800 http://dx.doi.org/10.1107/S1600536811055395 Text en © Abduelftah et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Abduelftah, Halema Shaban
Qasem Ali, Amna
Eltayeb, Naser Eltaher
Teoh, Siang Guan
Fun, Hoong-Kun
Bis{2-[3-(hy­droxy­imino-κN)butan-2-yl­idene]-N-methyl­hydrazinecarbothio­amide-κ(2) N (2),S}nickel(II) dichloride
title Bis{2-[3-(hy­droxy­imino-κN)butan-2-yl­idene]-N-methyl­hydrazinecarbothio­amide-κ(2) N (2),S}nickel(II) dichloride
title_full Bis{2-[3-(hy­droxy­imino-κN)butan-2-yl­idene]-N-methyl­hydrazinecarbothio­amide-κ(2) N (2),S}nickel(II) dichloride
title_fullStr Bis{2-[3-(hy­droxy­imino-κN)butan-2-yl­idene]-N-methyl­hydrazinecarbothio­amide-κ(2) N (2),S}nickel(II) dichloride
title_full_unstemmed Bis{2-[3-(hy­droxy­imino-κN)butan-2-yl­idene]-N-methyl­hydrazinecarbothio­amide-κ(2) N (2),S}nickel(II) dichloride
title_short Bis{2-[3-(hy­droxy­imino-κN)butan-2-yl­idene]-N-methyl­hydrazinecarbothio­amide-κ(2) N (2),S}nickel(II) dichloride
title_sort bis{2-[3-(hy­droxy­imino-κn)butan-2-yl­idene]-n-methyl­hydrazinecarbothio­amide-κ(2) n (2),s}nickel(ii) dichloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274853/
https://www.ncbi.nlm.nih.gov/pubmed/22346800
http://dx.doi.org/10.1107/S1600536811055395
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