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Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III)
The title compound, (C(8)H(20)N)[Tb(C(5)HF(6)O(2))(4)], is a tetrakis β-diketonate complex of hexafluoroacetylacetone with terbium(III), and tetraethylammonium as the counter-ion. This compound shows typical green terbium(III) luminescence upon excitation at about 335 nm. The coordination geome...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274855/ https://www.ncbi.nlm.nih.gov/pubmed/22346802 http://dx.doi.org/10.1107/S1600536811055437 |
| _version_ | 1782223120560553984 |
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| author | Van Deun, Rik Van Der Voort, Pascal Van Driessche, Isabel Van Hecke, Kristof |
| author_facet | Van Deun, Rik Van Der Voort, Pascal Van Driessche, Isabel Van Hecke, Kristof |
| author_sort | Van Deun, Rik |
| collection | PubMed |
| description | The title compound, (C(8)H(20)N)[Tb(C(5)HF(6)O(2))(4)], is a tetrakis β-diketonate complex of hexafluoroacetylacetone with terbium(III), and tetraethylammonium as the counter-ion. This compound shows typical green terbium(III) luminescence upon excitation at about 335 nm. The coordination geometry around the Tb(III) atom is a slightly distorted square antiprism. One hexafluoroacetylacetone ligand has a disordered CF(3) group [occupancies of 0.575 (4) and 0.425 (4)]. A three-dimensional network is built up by linkage of Tb(III) complexes via C—H⋯F interactions. |
| format | Online Article Text |
| id | pubmed-3274855 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32748552012-02-15 Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III) Van Deun, Rik Van Der Voort, Pascal Van Driessche, Isabel Van Hecke, Kristof Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(8)H(20)N)[Tb(C(5)HF(6)O(2))(4)], is a tetrakis β-diketonate complex of hexafluoroacetylacetone with terbium(III), and tetraethylammonium as the counter-ion. This compound shows typical green terbium(III) luminescence upon excitation at about 335 nm. The coordination geometry around the Tb(III) atom is a slightly distorted square antiprism. One hexafluoroacetylacetone ligand has a disordered CF(3) group [occupancies of 0.575 (4) and 0.425 (4)]. A three-dimensional network is built up by linkage of Tb(III) complexes via C—H⋯F interactions. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3274855/ /pubmed/22346802 http://dx.doi.org/10.1107/S1600536811055437 Text en © Van Deun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Van Deun, Rik Van Der Voort, Pascal Van Driessche, Isabel Van Hecke, Kristof Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III) |
| title | Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III) |
| title_full | Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III) |
| title_fullStr | Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III) |
| title_full_unstemmed | Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III) |
| title_short | Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III) |
| title_sort | tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274855/ https://www.ncbi.nlm.nih.gov/pubmed/22346802 http://dx.doi.org/10.1107/S1600536811055437 |
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