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Butyl­bis­(diphenyl­glyoximato)(pyridine-κN)­cobalt(III)

In the title compound, [Co(C(4)H(9))(C(14)H(11)N(2)O(2))(2)(C(5)H(5)N)], the Co(III) atom is coordinated by a butyl group, a nitro­gen-bonded pyridine and two N,N′-bidentate diphenyl­glyoximate ligands in a distorted octa­hedral geometry. The crystal structure features two short O—H⋯O bridges betwee...

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Detalles Bibliográficos
Autores principales: Kumar, Sarvendra, Thapa, Suresh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274857/
https://www.ncbi.nlm.nih.gov/pubmed/22346804
http://dx.doi.org/10.1107/S1600536812000153
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author Kumar, Sarvendra
Thapa, Suresh
author_facet Kumar, Sarvendra
Thapa, Suresh
author_sort Kumar, Sarvendra
collection PubMed
description In the title compound, [Co(C(4)H(9))(C(14)H(11)N(2)O(2))(2)(C(5)H(5)N)], the Co(III) atom is coordinated by a butyl group, a nitro­gen-bonded pyridine and two N,N′-bidentate diphenyl­glyoximate ligands in a distorted octa­hedral geometry. The crystal structure features two short O—H⋯O bridges between the two chelating anions, with O⋯O distances less than 2.5 Å.
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spelling pubmed-32748572012-02-15 Butyl­bis­(diphenyl­glyoximato)(pyridine-κN)­cobalt(III) Kumar, Sarvendra Thapa, Suresh Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(4)H(9))(C(14)H(11)N(2)O(2))(2)(C(5)H(5)N)], the Co(III) atom is coordinated by a butyl group, a nitro­gen-bonded pyridine and two N,N′-bidentate diphenyl­glyoximate ligands in a distorted octa­hedral geometry. The crystal structure features two short O—H⋯O bridges between the two chelating anions, with O⋯O distances less than 2.5 Å. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3274857/ /pubmed/22346804 http://dx.doi.org/10.1107/S1600536812000153 Text en © Kumar and Thapa 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kumar, Sarvendra
Thapa, Suresh
Butyl­bis­(diphenyl­glyoximato)(pyridine-κN)­cobalt(III)
title Butyl­bis­(diphenyl­glyoximato)(pyridine-κN)­cobalt(III)
title_full Butyl­bis­(diphenyl­glyoximato)(pyridine-κN)­cobalt(III)
title_fullStr Butyl­bis­(diphenyl­glyoximato)(pyridine-κN)­cobalt(III)
title_full_unstemmed Butyl­bis­(diphenyl­glyoximato)(pyridine-κN)­cobalt(III)
title_short Butyl­bis­(diphenyl­glyoximato)(pyridine-κN)­cobalt(III)
title_sort butyl­bis­(diphenyl­glyoximato)(pyridine-κn)­cobalt(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274857/
https://www.ncbi.nlm.nih.gov/pubmed/22346804
http://dx.doi.org/10.1107/S1600536812000153
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