Cargando…
Decacarbonyl[μ(4)-(ethane-1,2-diyldinitrilo)tetrakis(methanethiolato)]bis(triphenylphosphane)tetrairon(2 Fe—Fe)
In the title compound, [Fe(4)(C(6)H(12)N(2)S(4))(C(18)H(15)P)(2)(CO)(10)], the unit cell contains one molecule, which exhibits a crystallographically imposed center of symmetry. The independent Fe(2)S(2) fragment [Fe—Fe = 2.527 (1) Å] is in a butterfly conformation, and each Fe atom displays a pseu...
| Autores principales: | , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274859/ https://www.ncbi.nlm.nih.gov/pubmed/22346806 http://dx.doi.org/10.1107/S160053681105584X |
| Sumario: | In the title compound, [Fe(4)(C(6)H(12)N(2)S(4))(C(18)H(15)P)(2)(CO)(10)], the unit cell contains one molecule, which exhibits a crystallographically imposed center of symmetry. The independent Fe(2)S(2) fragment [Fe—Fe = 2.527 (1) Å] is in a butterfly conformation, and each Fe atom displays a pseudo-square-pyramidal coordination geometry. The phosphane group occupies an apical position [Fe—P = 2.2670 (14) Å]. In the crystal, weak intermolecular C—H⋯O hydrogen bonds link the molecules into chains along [110]. |
|---|