Decacarbon­yl[μ(4)-(ethane-1,2-diyl­dinitrilo)­tetra­kis­(methane­thiol­ato)]bis(triphenyl­phosphane)tetra­iron(2 Fe—Fe)

In the title compound, [Fe(4)(C(6)H(12)N(2)S(4))(C(18)H(15)P)(2)(CO)(10)], the unit cell contains one mol­ecule, which exhibits a crystallographically imposed center of symmetry. The independent Fe(2)S(2) fragment [Fe—Fe = 2.527 (1) Å] is in a butterfly conformation, and each Fe atom displays a pseu...

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Detalles Bibliográficos
Autores principales: Gao, Wei-Ming, Li, Jia-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274859/
https://www.ncbi.nlm.nih.gov/pubmed/22346806
http://dx.doi.org/10.1107/S160053681105584X
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author Gao, Wei-Ming
Li, Jia-Ming
author_facet Gao, Wei-Ming
Li, Jia-Ming
author_sort Gao, Wei-Ming
collection PubMed
description In the title compound, [Fe(4)(C(6)H(12)N(2)S(4))(C(18)H(15)P)(2)(CO)(10)], the unit cell contains one mol­ecule, which exhibits a crystallographically imposed center of symmetry. The independent Fe(2)S(2) fragment [Fe—Fe = 2.527 (1) Å] is in a butterfly conformation, and each Fe atom displays a pseudo-square-pyramidal coordination geometry. The phosphane group occupies an apical position [Fe—P = 2.2670 (14) Å]. In the crystal, weak inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into chains along [110].
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spelling pubmed-32748592012-02-15 Decacarbon­yl[μ(4)-(ethane-1,2-diyl­dinitrilo)­tetra­kis­(methane­thiol­ato)]bis(triphenyl­phosphane)tetra­iron(2 Fe—Fe) Gao, Wei-Ming Li, Jia-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(4)(C(6)H(12)N(2)S(4))(C(18)H(15)P)(2)(CO)(10)], the unit cell contains one mol­ecule, which exhibits a crystallographically imposed center of symmetry. The independent Fe(2)S(2) fragment [Fe—Fe = 2.527 (1) Å] is in a butterfly conformation, and each Fe atom displays a pseudo-square-pyramidal coordination geometry. The phosphane group occupies an apical position [Fe—P = 2.2670 (14) Å]. In the crystal, weak inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into chains along [110]. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3274859/ /pubmed/22346806 http://dx.doi.org/10.1107/S160053681105584X Text en © Gao and Li 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Wei-Ming
Li, Jia-Ming
Decacarbon­yl[μ(4)-(ethane-1,2-diyl­dinitrilo)­tetra­kis­(methane­thiol­ato)]bis(triphenyl­phosphane)tetra­iron(2 Fe—Fe)
title Decacarbon­yl[μ(4)-(ethane-1,2-diyl­dinitrilo)­tetra­kis­(methane­thiol­ato)]bis(triphenyl­phosphane)tetra­iron(2 Fe—Fe)
title_full Decacarbon­yl[μ(4)-(ethane-1,2-diyl­dinitrilo)­tetra­kis­(methane­thiol­ato)]bis(triphenyl­phosphane)tetra­iron(2 Fe—Fe)
title_fullStr Decacarbon­yl[μ(4)-(ethane-1,2-diyl­dinitrilo)­tetra­kis­(methane­thiol­ato)]bis(triphenyl­phosphane)tetra­iron(2 Fe—Fe)
title_full_unstemmed Decacarbon­yl[μ(4)-(ethane-1,2-diyl­dinitrilo)­tetra­kis­(methane­thiol­ato)]bis(triphenyl­phosphane)tetra­iron(2 Fe—Fe)
title_short Decacarbon­yl[μ(4)-(ethane-1,2-diyl­dinitrilo)­tetra­kis­(methane­thiol­ato)]bis(triphenyl­phosphane)tetra­iron(2 Fe—Fe)
title_sort decacarbon­yl[μ(4)-(ethane-1,2-diyl­dinitrilo)­tetra­kis­(methane­thiol­ato)]bis(triphenyl­phosphane)tetra­iron(2 fe—fe)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274859/
https://www.ncbi.nlm.nih.gov/pubmed/22346806
http://dx.doi.org/10.1107/S160053681105584X
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