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Bis(2-{[2-(2-hydroxybenzylamino)ethyl]aminomethyl}phenolato-κ(3) N,N′,O (1))cobalt(III) nitrate monohydrate
In the title compound, [Co(C(16)H(19)N(2)O(2))(2)]NO(3)·H(2)O, the Co(III) ion is located on an inversion center and is six-coordinated by two phenolate O atoms and four amino N atoms from two diamine ligands, forming an octahedral geometry. The water molecule and the nitrate anion are located clo...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274862/ https://www.ncbi.nlm.nih.gov/pubmed/22346809 http://dx.doi.org/10.1107/S1600536811055851 |
Sumario: | In the title compound, [Co(C(16)H(19)N(2)O(2))(2)]NO(3)·H(2)O, the Co(III) ion is located on an inversion center and is six-coordinated by two phenolate O atoms and four amino N atoms from two diamine ligands, forming an octahedral geometry. The water molecule and the nitrate anion are located close to an inversion center, and are thus equally disordered by symmetry. The crystal packing is stabilized by intermolecular O—H⋯O hydrogen bonds involving the uncoordinated water molecule and the free phenol hydroxyl group with the nitrate anion. N—H⋯O hydrogen bonds involving the amino groups and the nitrate anions connect the complex molecules along the c axis. |
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