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Bis(2-{[2-(2-hydroxybenzylamino)ethyl]aminomethyl}phenolato-κ(3) N,N′,O (1))cobalt(III) nitrate monohydrate
In the title compound, [Co(C(16)H(19)N(2)O(2))(2)]NO(3)·H(2)O, the Co(III) ion is located on an inversion center and is six-coordinated by two phenolate O atoms and four amino N atoms from two diamine ligands, forming an octahedral geometry. The water molecule and the nitrate anion are located clo...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274862/ https://www.ncbi.nlm.nih.gov/pubmed/22346809 http://dx.doi.org/10.1107/S1600536811055851 |
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author | Sow, Mouhamadou Moustapha Diouf, Ousmane Thiam, Ibrahima Elhadj Gaye, Mohamed Retailleau, Pascal |
author_facet | Sow, Mouhamadou Moustapha Diouf, Ousmane Thiam, Ibrahima Elhadj Gaye, Mohamed Retailleau, Pascal |
author_sort | Sow, Mouhamadou Moustapha |
collection | PubMed |
description | In the title compound, [Co(C(16)H(19)N(2)O(2))(2)]NO(3)·H(2)O, the Co(III) ion is located on an inversion center and is six-coordinated by two phenolate O atoms and four amino N atoms from two diamine ligands, forming an octahedral geometry. The water molecule and the nitrate anion are located close to an inversion center, and are thus equally disordered by symmetry. The crystal packing is stabilized by intermolecular O—H⋯O hydrogen bonds involving the uncoordinated water molecule and the free phenol hydroxyl group with the nitrate anion. N—H⋯O hydrogen bonds involving the amino groups and the nitrate anions connect the complex molecules along the c axis. |
format | Online Article Text |
id | pubmed-3274862 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32748622012-02-15 Bis(2-{[2-(2-hydroxybenzylamino)ethyl]aminomethyl}phenolato-κ(3) N,N′,O (1))cobalt(III) nitrate monohydrate Sow, Mouhamadou Moustapha Diouf, Ousmane Thiam, Ibrahima Elhadj Gaye, Mohamed Retailleau, Pascal Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(16)H(19)N(2)O(2))(2)]NO(3)·H(2)O, the Co(III) ion is located on an inversion center and is six-coordinated by two phenolate O atoms and four amino N atoms from two diamine ligands, forming an octahedral geometry. The water molecule and the nitrate anion are located close to an inversion center, and are thus equally disordered by symmetry. The crystal packing is stabilized by intermolecular O—H⋯O hydrogen bonds involving the uncoordinated water molecule and the free phenol hydroxyl group with the nitrate anion. N—H⋯O hydrogen bonds involving the amino groups and the nitrate anions connect the complex molecules along the c axis. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3274862/ /pubmed/22346809 http://dx.doi.org/10.1107/S1600536811055851 Text en © Sow et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sow, Mouhamadou Moustapha Diouf, Ousmane Thiam, Ibrahima Elhadj Gaye, Mohamed Retailleau, Pascal Bis(2-{[2-(2-hydroxybenzylamino)ethyl]aminomethyl}phenolato-κ(3) N,N′,O (1))cobalt(III) nitrate monohydrate |
title | Bis(2-{[2-(2-hydroxybenzylamino)ethyl]aminomethyl}phenolato-κ(3)
N,N′,O
(1))cobalt(III) nitrate monohydrate |
title_full | Bis(2-{[2-(2-hydroxybenzylamino)ethyl]aminomethyl}phenolato-κ(3)
N,N′,O
(1))cobalt(III) nitrate monohydrate |
title_fullStr | Bis(2-{[2-(2-hydroxybenzylamino)ethyl]aminomethyl}phenolato-κ(3)
N,N′,O
(1))cobalt(III) nitrate monohydrate |
title_full_unstemmed | Bis(2-{[2-(2-hydroxybenzylamino)ethyl]aminomethyl}phenolato-κ(3)
N,N′,O
(1))cobalt(III) nitrate monohydrate |
title_short | Bis(2-{[2-(2-hydroxybenzylamino)ethyl]aminomethyl}phenolato-κ(3)
N,N′,O
(1))cobalt(III) nitrate monohydrate |
title_sort | bis(2-{[2-(2-hydroxybenzylamino)ethyl]aminomethyl}phenolato-κ(3)
n,n′,o
(1))cobalt(iii) nitrate monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274862/ https://www.ncbi.nlm.nih.gov/pubmed/22346809 http://dx.doi.org/10.1107/S1600536811055851 |
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