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Bis(2-{[2-(2-hy­droxy­benzyl­amino)­eth­yl]amino­meth­yl}phenolato-κ(3) N,N′,O (1))cobalt(III) nitrate monohydrate

In the title compound, [Co(C(16)H(19)N(2)O(2))(2)]NO(3)·H(2)O, the Co(III) ion is located on an inversion center and is six-coordinated by two phenolate O atoms and four amino N atoms from two diamine ligands, forming an octa­hedral geometry. The water mol­ecule and the nitrate anion are located clo...

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Autores principales: Sow, Mouhamadou Moustapha, Diouf, Ousmane, Thiam, Ibrahima Elhadj, Gaye, Mohamed, Retailleau, Pascal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274862/
https://www.ncbi.nlm.nih.gov/pubmed/22346809
http://dx.doi.org/10.1107/S1600536811055851
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author Sow, Mouhamadou Moustapha
Diouf, Ousmane
Thiam, Ibrahima Elhadj
Gaye, Mohamed
Retailleau, Pascal
author_facet Sow, Mouhamadou Moustapha
Diouf, Ousmane
Thiam, Ibrahima Elhadj
Gaye, Mohamed
Retailleau, Pascal
author_sort Sow, Mouhamadou Moustapha
collection PubMed
description In the title compound, [Co(C(16)H(19)N(2)O(2))(2)]NO(3)·H(2)O, the Co(III) ion is located on an inversion center and is six-coordinated by two phenolate O atoms and four amino N atoms from two diamine ligands, forming an octa­hedral geometry. The water mol­ecule and the nitrate anion are located close to an inversion center, and are thus equally disordered by symmetry. The crystal packing is stabilized by inter­molecular O—H⋯O hydrogen bonds involving the uncoordinated water mol­ecule and the free phenol hydroxyl group with the nitrate anion. N—H⋯O hydrogen bonds involving the amino groups and the nitrate anions connect the complex mol­ecules along the c axis.
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spelling pubmed-32748622012-02-15 Bis(2-{[2-(2-hy­droxy­benzyl­amino)­eth­yl]amino­meth­yl}phenolato-κ(3) N,N′,O (1))cobalt(III) nitrate monohydrate Sow, Mouhamadou Moustapha Diouf, Ousmane Thiam, Ibrahima Elhadj Gaye, Mohamed Retailleau, Pascal Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(16)H(19)N(2)O(2))(2)]NO(3)·H(2)O, the Co(III) ion is located on an inversion center and is six-coordinated by two phenolate O atoms and four amino N atoms from two diamine ligands, forming an octa­hedral geometry. The water mol­ecule and the nitrate anion are located close to an inversion center, and are thus equally disordered by symmetry. The crystal packing is stabilized by inter­molecular O—H⋯O hydrogen bonds involving the uncoordinated water mol­ecule and the free phenol hydroxyl group with the nitrate anion. N—H⋯O hydrogen bonds involving the amino groups and the nitrate anions connect the complex mol­ecules along the c axis. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3274862/ /pubmed/22346809 http://dx.doi.org/10.1107/S1600536811055851 Text en © Sow et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sow, Mouhamadou Moustapha
Diouf, Ousmane
Thiam, Ibrahima Elhadj
Gaye, Mohamed
Retailleau, Pascal
Bis(2-{[2-(2-hy­droxy­benzyl­amino)­eth­yl]amino­meth­yl}phenolato-κ(3) N,N′,O (1))cobalt(III) nitrate monohydrate
title Bis(2-{[2-(2-hy­droxy­benzyl­amino)­eth­yl]amino­meth­yl}phenolato-κ(3) N,N′,O (1))cobalt(III) nitrate monohydrate
title_full Bis(2-{[2-(2-hy­droxy­benzyl­amino)­eth­yl]amino­meth­yl}phenolato-κ(3) N,N′,O (1))cobalt(III) nitrate monohydrate
title_fullStr Bis(2-{[2-(2-hy­droxy­benzyl­amino)­eth­yl]amino­meth­yl}phenolato-κ(3) N,N′,O (1))cobalt(III) nitrate monohydrate
title_full_unstemmed Bis(2-{[2-(2-hy­droxy­benzyl­amino)­eth­yl]amino­meth­yl}phenolato-κ(3) N,N′,O (1))cobalt(III) nitrate monohydrate
title_short Bis(2-{[2-(2-hy­droxy­benzyl­amino)­eth­yl]amino­meth­yl}phenolato-κ(3) N,N′,O (1))cobalt(III) nitrate monohydrate
title_sort bis(2-{[2-(2-hy­droxy­benzyl­amino)­eth­yl]amino­meth­yl}phenolato-κ(3) n,n′,o (1))cobalt(iii) nitrate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274862/
https://www.ncbi.nlm.nih.gov/pubmed/22346809
http://dx.doi.org/10.1107/S1600536811055851
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