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Bis(acetato-κ(2) O,O′)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)manganese(II) dihydrate
The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(15)H(11)N(3))]·2H(2)O, is seven-coordinated in a considerably distorted pentagonal–bipyramidal geometry by three N atoms of the tridentate 2,2′:6′,2′′-terpyridine ligand and four O atoms from two acetate anions which chelate the Mn atom via...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274864/ https://www.ncbi.nlm.nih.gov/pubmed/22346811 http://dx.doi.org/10.1107/S1600536811055802 |
Sumario: | The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(15)H(11)N(3))]·2H(2)O, is seven-coordinated in a considerably distorted pentagonal–bipyramidal geometry by three N atoms of the tridentate 2,2′:6′,2′′-terpyridine ligand and four O atoms from two acetate anions which chelate the Mn atom via two O atoms. The lateral pyridine rings are slightly inclined to the central pyridine ring, making dihedral angles of 13.6 (2) and 5.7 (2)°. The complex and solvent water molecules are linked by intermolecular O—H⋯O hydrogen bonds into a three-dimensional network. |
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