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Bis(acetato-κ(2) O,O′)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)manganese(II) dihydrate
The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(15)H(11)N(3))]·2H(2)O, is seven-coordinated in a considerably distorted pentagonal–bipyramidal geometry by three N atoms of the tridentate 2,2′:6′,2′′-terpyridine ligand and four O atoms from two acetate anions which chelate the Mn atom via...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274864/ https://www.ncbi.nlm.nih.gov/pubmed/22346811 http://dx.doi.org/10.1107/S1600536811055802 |
| _version_ | 1782223122702794752 |
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| author | Ha, Kwang |
| author_facet | Ha, Kwang |
| author_sort | Ha, Kwang |
| collection | PubMed |
| description | The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(15)H(11)N(3))]·2H(2)O, is seven-coordinated in a considerably distorted pentagonal–bipyramidal geometry by three N atoms of the tridentate 2,2′:6′,2′′-terpyridine ligand and four O atoms from two acetate anions which chelate the Mn atom via two O atoms. The lateral pyridine rings are slightly inclined to the central pyridine ring, making dihedral angles of 13.6 (2) and 5.7 (2)°. The complex and solvent water molecules are linked by intermolecular O—H⋯O hydrogen bonds into a three-dimensional network. |
| format | Online Article Text |
| id | pubmed-3274864 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32748642012-02-15 Bis(acetato-κ(2) O,O′)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)manganese(II) dihydrate Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(15)H(11)N(3))]·2H(2)O, is seven-coordinated in a considerably distorted pentagonal–bipyramidal geometry by three N atoms of the tridentate 2,2′:6′,2′′-terpyridine ligand and four O atoms from two acetate anions which chelate the Mn atom via two O atoms. The lateral pyridine rings are slightly inclined to the central pyridine ring, making dihedral angles of 13.6 (2) and 5.7 (2)°. The complex and solvent water molecules are linked by intermolecular O—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3274864/ /pubmed/22346811 http://dx.doi.org/10.1107/S1600536811055802 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ha, Kwang Bis(acetato-κ(2) O,O′)(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)manganese(II) dihydrate |
| title | Bis(acetato-κ(2)
O,O′)(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)manganese(II) dihydrate |
| title_full | Bis(acetato-κ(2)
O,O′)(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)manganese(II) dihydrate |
| title_fullStr | Bis(acetato-κ(2)
O,O′)(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)manganese(II) dihydrate |
| title_full_unstemmed | Bis(acetato-κ(2)
O,O′)(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)manganese(II) dihydrate |
| title_short | Bis(acetato-κ(2)
O,O′)(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)manganese(II) dihydrate |
| title_sort | bis(acetato-κ(2)
o,o′)(2,2′:6′,2′′-terpyridine-κ(3)
n,n′,n′′)manganese(ii) dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274864/ https://www.ncbi.nlm.nih.gov/pubmed/22346811 http://dx.doi.org/10.1107/S1600536811055802 |
| work_keys_str_mv | AT hakwang bisacetatok2oo2262terpyridinek3nnnmanganeseiidihydrate |