Poly[[μ(2)-1,3-bis­(imidazol-1-ylmeth­yl)benzene][μ(2)-2,2′-dihy­droxy-1,1′-methyl­enebis(naphthalene-3-carboxyl­ato)]zinc]

In the title compound, [Zn(C(23)H(14)O(6))(C(14)H(14)N(4))](n), the Zn(II) ion is four-coordinated in a distorted tetra­hedral geometry. The 1,3-bis­(imidazol-1-ylmeth­yl)benzene and 2,2′-dihy­droxy-1,1′-methyl­enebis(naphthalene-3-carboxy­l­ate) ligands con­nect the Zn(II) ions alternately in diffe...

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Detalles Bibliográficos
Autores principales: Peng, Yanqiang, Wei, Xilian, Li, Dacheng, Wang, Suna
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274865/
https://www.ncbi.nlm.nih.gov/pubmed/22346812
http://dx.doi.org/10.1107/S1600536811054584
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author Peng, Yanqiang
Wei, Xilian
Li, Dacheng
Wang, Suna
author_facet Peng, Yanqiang
Wei, Xilian
Li, Dacheng
Wang, Suna
author_sort Peng, Yanqiang
collection PubMed
description In the title compound, [Zn(C(23)H(14)O(6))(C(14)H(14)N(4))](n), the Zn(II) ion is four-coordinated in a distorted tetra­hedral geometry. The 1,3-bis­(imidazol-1-ylmeth­yl)benzene and 2,2′-dihy­droxy-1,1′-methyl­enebis(naphthalene-3-carboxy­l­ate) ligands con­nect the Zn(II) ions alternately in different directions, forming a layered structure parallel to the ac plane. Topological analysis reveals that the whole structure is a (4,4) network. The layers are further assembled into a three-dimensional supra­molecular structure via C—H⋯O and C—H⋯π inter­actions.
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spelling pubmed-32748652012-02-15 Poly[[μ(2)-1,3-bis­(imidazol-1-ylmeth­yl)benzene][μ(2)-2,2′-dihy­droxy-1,1′-methyl­enebis(naphthalene-3-carboxyl­ato)]zinc] Peng, Yanqiang Wei, Xilian Li, Dacheng Wang, Suna Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(23)H(14)O(6))(C(14)H(14)N(4))](n), the Zn(II) ion is four-coordinated in a distorted tetra­hedral geometry. The 1,3-bis­(imidazol-1-ylmeth­yl)benzene and 2,2′-dihy­droxy-1,1′-methyl­enebis(naphthalene-3-carboxy­l­ate) ligands con­nect the Zn(II) ions alternately in different directions, forming a layered structure parallel to the ac plane. Topological analysis reveals that the whole structure is a (4,4) network. The layers are further assembled into a three-dimensional supra­molecular structure via C—H⋯O and C—H⋯π inter­actions. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3274865/ /pubmed/22346812 http://dx.doi.org/10.1107/S1600536811054584 Text en © Peng et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Peng, Yanqiang
Wei, Xilian
Li, Dacheng
Wang, Suna
Poly[[μ(2)-1,3-bis­(imidazol-1-ylmeth­yl)benzene][μ(2)-2,2′-dihy­droxy-1,1′-methyl­enebis(naphthalene-3-carboxyl­ato)]zinc]
title Poly[[μ(2)-1,3-bis­(imidazol-1-ylmeth­yl)benzene][μ(2)-2,2′-dihy­droxy-1,1′-methyl­enebis(naphthalene-3-carboxyl­ato)]zinc]
title_full Poly[[μ(2)-1,3-bis­(imidazol-1-ylmeth­yl)benzene][μ(2)-2,2′-dihy­droxy-1,1′-methyl­enebis(naphthalene-3-carboxyl­ato)]zinc]
title_fullStr Poly[[μ(2)-1,3-bis­(imidazol-1-ylmeth­yl)benzene][μ(2)-2,2′-dihy­droxy-1,1′-methyl­enebis(naphthalene-3-carboxyl­ato)]zinc]
title_full_unstemmed Poly[[μ(2)-1,3-bis­(imidazol-1-ylmeth­yl)benzene][μ(2)-2,2′-dihy­droxy-1,1′-methyl­enebis(naphthalene-3-carboxyl­ato)]zinc]
title_short Poly[[μ(2)-1,3-bis­(imidazol-1-ylmeth­yl)benzene][μ(2)-2,2′-dihy­droxy-1,1′-methyl­enebis(naphthalene-3-carboxyl­ato)]zinc]
title_sort poly[[μ(2)-1,3-bis­(imidazol-1-ylmeth­yl)benzene][μ(2)-2,2′-dihy­droxy-1,1′-methyl­enebis(naphthalene-3-carboxyl­ato)]zinc]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274865/
https://www.ncbi.nlm.nih.gov/pubmed/22346812
http://dx.doi.org/10.1107/S1600536811054584
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AT lidacheng polym213bisimidazol1ylmethylbenzenem222dihydroxy11methylenebisnaphthalene3carboxylatozinc
AT wangsuna polym213bisimidazol1ylmethylbenzenem222dihydroxy11methylenebisnaphthalene3carboxylatozinc

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