Cargando…

Diaqua­bis­(N,N-diethyl­pyridine-3-carboxamide-κN (1))bis­{4-[2-(2,4-dioxopentan-3-yl­idene)hydrazin-1-yl]benzoato-κO}copper(II)

In the title compound, [Cu(C(12)H(11)N(2)O(4))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Cu(II) atom lies on a center of inversion and is coordinated by carboxyl­ate O atoms, pyridine N atoms and two water mol­ecules in an elongated octa­hedral geometry. The pyridine ring is oriented at a dihedral angl...

Descripción completa

Detalles Bibliográficos
Autores principales: Alieva, Rafiqa A., Mardanova, Vusala I., Chyraqov, Famil M., Gurbanov, Atash V., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274866/
https://www.ncbi.nlm.nih.gov/pubmed/22346813
http://dx.doi.org/10.1107/S1600536811056200
_version_ 1782223123173605376
author Alieva, Rafiqa A.
Mardanova, Vusala I.
Chyraqov, Famil M.
Gurbanov, Atash V.
Ng, Seik Weng
author_facet Alieva, Rafiqa A.
Mardanova, Vusala I.
Chyraqov, Famil M.
Gurbanov, Atash V.
Ng, Seik Weng
author_sort Alieva, Rafiqa A.
collection PubMed
description In the title compound, [Cu(C(12)H(11)N(2)O(4))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Cu(II) atom lies on a center of inversion and is coordinated by carboxyl­ate O atoms, pyridine N atoms and two water mol­ecules in an elongated octa­hedral geometry. The pyridine ring is oriented at a dihedral angle of 74.83 (12)° with respect to the benzene ring. Intra­molecular O—H⋯O and N—H⋯O hydrogen bonding is observed. The water mol­ecule is a hydrogen-bond donor to the carbonyl O atom of an adjacent carboxyl­ate group, generating a chain running along the a axis. One of the ethyl groups is disordered over two sets of sites in a 0.787 (5):0.213 ratio.
format Online
Article
Text
id pubmed-3274866
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32748662012-02-15 Diaqua­bis­(N,N-diethyl­pyridine-3-carboxamide-κN (1))bis­{4-[2-(2,4-dioxopentan-3-yl­idene)hydrazin-1-yl]benzoato-κO}copper(II) Alieva, Rafiqa A. Mardanova, Vusala I. Chyraqov, Famil M. Gurbanov, Atash V. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(12)H(11)N(2)O(4))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Cu(II) atom lies on a center of inversion and is coordinated by carboxyl­ate O atoms, pyridine N atoms and two water mol­ecules in an elongated octa­hedral geometry. The pyridine ring is oriented at a dihedral angle of 74.83 (12)° with respect to the benzene ring. Intra­molecular O—H⋯O and N—H⋯O hydrogen bonding is observed. The water mol­ecule is a hydrogen-bond donor to the carbonyl O atom of an adjacent carboxyl­ate group, generating a chain running along the a axis. One of the ethyl groups is disordered over two sets of sites in a 0.787 (5):0.213 ratio. International Union of Crystallography 2012-01-11 /pmc/articles/PMC3274866/ /pubmed/22346813 http://dx.doi.org/10.1107/S1600536811056200 Text en © Alieva et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Alieva, Rafiqa A.
Mardanova, Vusala I.
Chyraqov, Famil M.
Gurbanov, Atash V.
Ng, Seik Weng
Diaqua­bis­(N,N-diethyl­pyridine-3-carboxamide-κN (1))bis­{4-[2-(2,4-dioxopentan-3-yl­idene)hydrazin-1-yl]benzoato-κO}copper(II)
title Diaqua­bis­(N,N-diethyl­pyridine-3-carboxamide-κN (1))bis­{4-[2-(2,4-dioxopentan-3-yl­idene)hydrazin-1-yl]benzoato-κO}copper(II)
title_full Diaqua­bis­(N,N-diethyl­pyridine-3-carboxamide-κN (1))bis­{4-[2-(2,4-dioxopentan-3-yl­idene)hydrazin-1-yl]benzoato-κO}copper(II)
title_fullStr Diaqua­bis­(N,N-diethyl­pyridine-3-carboxamide-κN (1))bis­{4-[2-(2,4-dioxopentan-3-yl­idene)hydrazin-1-yl]benzoato-κO}copper(II)
title_full_unstemmed Diaqua­bis­(N,N-diethyl­pyridine-3-carboxamide-κN (1))bis­{4-[2-(2,4-dioxopentan-3-yl­idene)hydrazin-1-yl]benzoato-κO}copper(II)
title_short Diaqua­bis­(N,N-diethyl­pyridine-3-carboxamide-κN (1))bis­{4-[2-(2,4-dioxopentan-3-yl­idene)hydrazin-1-yl]benzoato-κO}copper(II)
title_sort diaqua­bis­(n,n-diethyl­pyridine-3-carboxamide-κn (1))bis­{4-[2-(2,4-dioxopentan-3-yl­idene)hydrazin-1-yl]benzoato-κo}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274866/
https://www.ncbi.nlm.nih.gov/pubmed/22346813
http://dx.doi.org/10.1107/S1600536811056200
work_keys_str_mv AT alievarafiqaa diaquabisnndiethylpyridine3carboxamidekn1bis4224dioxopentan3ylidenehydrazin1ylbenzoatokocopperii
AT mardanovavusalai diaquabisnndiethylpyridine3carboxamidekn1bis4224dioxopentan3ylidenehydrazin1ylbenzoatokocopperii
AT chyraqovfamilm diaquabisnndiethylpyridine3carboxamidekn1bis4224dioxopentan3ylidenehydrazin1ylbenzoatokocopperii
AT gurbanovatashv diaquabisnndiethylpyridine3carboxamidekn1bis4224dioxopentan3ylidenehydrazin1ylbenzoatokocopperii
AT ngseikweng diaquabisnndiethylpyridine3carboxamidekn1bis4224dioxopentan3ylidenehydrazin1ylbenzoatokocopperii