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Diaquabis(N,N-diethylpyridine-3-carboxamide-κN (1))bis{4-[2-(2,4-dioxopentan-3-ylidene)hydrazin-1-yl]benzoato-κO}copper(II)
In the title compound, [Cu(C(12)H(11)N(2)O(4))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Cu(II) atom lies on a center of inversion and is coordinated by carboxylate O atoms, pyridine N atoms and two water molecules in an elongated octahedral geometry. The pyridine ring is oriented at a dihedral angl...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274866/ https://www.ncbi.nlm.nih.gov/pubmed/22346813 http://dx.doi.org/10.1107/S1600536811056200 |
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author | Alieva, Rafiqa A. Mardanova, Vusala I. Chyraqov, Famil M. Gurbanov, Atash V. Ng, Seik Weng |
author_facet | Alieva, Rafiqa A. Mardanova, Vusala I. Chyraqov, Famil M. Gurbanov, Atash V. Ng, Seik Weng |
author_sort | Alieva, Rafiqa A. |
collection | PubMed |
description | In the title compound, [Cu(C(12)H(11)N(2)O(4))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Cu(II) atom lies on a center of inversion and is coordinated by carboxylate O atoms, pyridine N atoms and two water molecules in an elongated octahedral geometry. The pyridine ring is oriented at a dihedral angle of 74.83 (12)° with respect to the benzene ring. Intramolecular O—H⋯O and N—H⋯O hydrogen bonding is observed. The water molecule is a hydrogen-bond donor to the carbonyl O atom of an adjacent carboxylate group, generating a chain running along the a axis. One of the ethyl groups is disordered over two sets of sites in a 0.787 (5):0.213 ratio. |
format | Online Article Text |
id | pubmed-3274866 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32748662012-02-15 Diaquabis(N,N-diethylpyridine-3-carboxamide-κN (1))bis{4-[2-(2,4-dioxopentan-3-ylidene)hydrazin-1-yl]benzoato-κO}copper(II) Alieva, Rafiqa A. Mardanova, Vusala I. Chyraqov, Famil M. Gurbanov, Atash V. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(12)H(11)N(2)O(4))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Cu(II) atom lies on a center of inversion and is coordinated by carboxylate O atoms, pyridine N atoms and two water molecules in an elongated octahedral geometry. The pyridine ring is oriented at a dihedral angle of 74.83 (12)° with respect to the benzene ring. Intramolecular O—H⋯O and N—H⋯O hydrogen bonding is observed. The water molecule is a hydrogen-bond donor to the carbonyl O atom of an adjacent carboxylate group, generating a chain running along the a axis. One of the ethyl groups is disordered over two sets of sites in a 0.787 (5):0.213 ratio. International Union of Crystallography 2012-01-11 /pmc/articles/PMC3274866/ /pubmed/22346813 http://dx.doi.org/10.1107/S1600536811056200 Text en © Alieva et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Alieva, Rafiqa A. Mardanova, Vusala I. Chyraqov, Famil M. Gurbanov, Atash V. Ng, Seik Weng Diaquabis(N,N-diethylpyridine-3-carboxamide-κN (1))bis{4-[2-(2,4-dioxopentan-3-ylidene)hydrazin-1-yl]benzoato-κO}copper(II) |
title | Diaquabis(N,N-diethylpyridine-3-carboxamide-κN
(1))bis{4-[2-(2,4-dioxopentan-3-ylidene)hydrazin-1-yl]benzoato-κO}copper(II) |
title_full | Diaquabis(N,N-diethylpyridine-3-carboxamide-κN
(1))bis{4-[2-(2,4-dioxopentan-3-ylidene)hydrazin-1-yl]benzoato-κO}copper(II) |
title_fullStr | Diaquabis(N,N-diethylpyridine-3-carboxamide-κN
(1))bis{4-[2-(2,4-dioxopentan-3-ylidene)hydrazin-1-yl]benzoato-κO}copper(II) |
title_full_unstemmed | Diaquabis(N,N-diethylpyridine-3-carboxamide-κN
(1))bis{4-[2-(2,4-dioxopentan-3-ylidene)hydrazin-1-yl]benzoato-κO}copper(II) |
title_short | Diaquabis(N,N-diethylpyridine-3-carboxamide-κN
(1))bis{4-[2-(2,4-dioxopentan-3-ylidene)hydrazin-1-yl]benzoato-κO}copper(II) |
title_sort | diaquabis(n,n-diethylpyridine-3-carboxamide-κn
(1))bis{4-[2-(2,4-dioxopentan-3-ylidene)hydrazin-1-yl]benzoato-κo}copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274866/ https://www.ncbi.nlm.nih.gov/pubmed/22346813 http://dx.doi.org/10.1107/S1600536811056200 |
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