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catena-Poly[[aqua­bis­{4-[2-(2,4-dioxopentan-3-yl­idene)hydrazin-1-yl]benzo­ato-κO}copper(II)]-μ-N,N-diethyl­pyridine-3-carboxamide-κ(2) N (1):O]

The Cu(II) atom in the title compound, [Cu(C(12)H(11)N(2)O(4))(2)(C(10)H(14)N(2)O)(H(2)O)](n), lies in a square plane defined by the O atoms of the carboxyl­ate ions, the N atom of the N-heterocycle and the water mol­ecule. Coordination by an amido O atom of an adjacent N-heterocycle in the apical d...

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Detalles Bibliográficos
Autores principales: Maharramov, Abel M., Mardanova, Vusala I., Chyraqov, Famil M., Gurbanov, Atash V., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274867/
https://www.ncbi.nlm.nih.gov/pubmed/22346814
http://dx.doi.org/10.1107/S1600536812000025
Descripción
Sumario:The Cu(II) atom in the title compound, [Cu(C(12)H(11)N(2)O(4))(2)(C(10)H(14)N(2)O)(H(2)O)](n), lies in a square plane defined by the O atoms of the carboxyl­ate ions, the N atom of the N-heterocycle and the water mol­ecule. Coordination by an amido O atom of an adjacent N-heterocycle in the apical direction leads to a polymeric chain running along [01[Image: see text]]. The chain motif is consolidated by hydrogen bonds involving the water mol­ecule; the water mol­ecule is a hydrogen-bond donor to the free carbonyl atoms of the carboxyl­ate ions. Intra­molecular N—H⋯O hydrogen bonds also occur.