catena-Poly[[aqua­bis­{4-[2-(2,4-dioxopentan-3-yl­idene)hydrazin-1-yl]benzo­ato-κO}copper(II)]-μ-N,N-diethyl­pyridine-3-carboxamide-κ(2) N (1):O]

The Cu(II) atom in the title compound, [Cu(C(12)H(11)N(2)O(4))(2)(C(10)H(14)N(2)O)(H(2)O)](n), lies in a square plane defined by the O atoms of the carboxyl­ate ions, the N atom of the N-heterocycle and the water mol­ecule. Coordination by an amido O atom of an adjacent N-heterocycle in the apical d...

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Detalles Bibliográficos
Autores principales: Maharramov, Abel M., Mardanova, Vusala I., Chyraqov, Famil M., Gurbanov, Atash V., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274867/
https://www.ncbi.nlm.nih.gov/pubmed/22346814
http://dx.doi.org/10.1107/S1600536812000025
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author Maharramov, Abel M.
Mardanova, Vusala I.
Chyraqov, Famil M.
Gurbanov, Atash V.
Ng, Seik Weng
author_facet Maharramov, Abel M.
Mardanova, Vusala I.
Chyraqov, Famil M.
Gurbanov, Atash V.
Ng, Seik Weng
author_sort Maharramov, Abel M.
collection PubMed
description The Cu(II) atom in the title compound, [Cu(C(12)H(11)N(2)O(4))(2)(C(10)H(14)N(2)O)(H(2)O)](n), lies in a square plane defined by the O atoms of the carboxyl­ate ions, the N atom of the N-heterocycle and the water mol­ecule. Coordination by an amido O atom of an adjacent N-heterocycle in the apical direction leads to a polymeric chain running along [01[Image: see text]]. The chain motif is consolidated by hydrogen bonds involving the water mol­ecule; the water mol­ecule is a hydrogen-bond donor to the free carbonyl atoms of the carboxyl­ate ions. Intra­molecular N—H⋯O hydrogen bonds also occur.
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spelling pubmed-32748672012-02-15 catena-Poly[[aqua­bis­{4-[2-(2,4-dioxopentan-3-yl­idene)hydrazin-1-yl]benzo­ato-κO}copper(II)]-μ-N,N-diethyl­pyridine-3-carboxamide-κ(2) N (1):O] Maharramov, Abel M. Mardanova, Vusala I. Chyraqov, Famil M. Gurbanov, Atash V. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(II) atom in the title compound, [Cu(C(12)H(11)N(2)O(4))(2)(C(10)H(14)N(2)O)(H(2)O)](n), lies in a square plane defined by the O atoms of the carboxyl­ate ions, the N atom of the N-heterocycle and the water mol­ecule. Coordination by an amido O atom of an adjacent N-heterocycle in the apical direction leads to a polymeric chain running along [01[Image: see text]]. The chain motif is consolidated by hydrogen bonds involving the water mol­ecule; the water mol­ecule is a hydrogen-bond donor to the free carbonyl atoms of the carboxyl­ate ions. Intra­molecular N—H⋯O hydrogen bonds also occur. International Union of Crystallography 2012-01-11 /pmc/articles/PMC3274867/ /pubmed/22346814 http://dx.doi.org/10.1107/S1600536812000025 Text en © Maharramov et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Maharramov, Abel M.
Mardanova, Vusala I.
Chyraqov, Famil M.
Gurbanov, Atash V.
Ng, Seik Weng
catena-Poly[[aqua­bis­{4-[2-(2,4-dioxopentan-3-yl­idene)hydrazin-1-yl]benzo­ato-κO}copper(II)]-μ-N,N-diethyl­pyridine-3-carboxamide-κ(2) N (1):O]
title catena-Poly[[aqua­bis­{4-[2-(2,4-dioxopentan-3-yl­idene)hydrazin-1-yl]benzo­ato-κO}copper(II)]-μ-N,N-diethyl­pyridine-3-carboxamide-κ(2) N (1):O]
title_full catena-Poly[[aqua­bis­{4-[2-(2,4-dioxopentan-3-yl­idene)hydrazin-1-yl]benzo­ato-κO}copper(II)]-μ-N,N-diethyl­pyridine-3-carboxamide-κ(2) N (1):O]
title_fullStr catena-Poly[[aqua­bis­{4-[2-(2,4-dioxopentan-3-yl­idene)hydrazin-1-yl]benzo­ato-κO}copper(II)]-μ-N,N-diethyl­pyridine-3-carboxamide-κ(2) N (1):O]
title_full_unstemmed catena-Poly[[aqua­bis­{4-[2-(2,4-dioxopentan-3-yl­idene)hydrazin-1-yl]benzo­ato-κO}copper(II)]-μ-N,N-diethyl­pyridine-3-carboxamide-κ(2) N (1):O]
title_short catena-Poly[[aqua­bis­{4-[2-(2,4-dioxopentan-3-yl­idene)hydrazin-1-yl]benzo­ato-κO}copper(II)]-μ-N,N-diethyl­pyridine-3-carboxamide-κ(2) N (1):O]
title_sort catena-poly[[aqua­bis­{4-[2-(2,4-dioxopentan-3-yl­idene)hydrazin-1-yl]benzo­ato-κo}copper(ii)]-μ-n,n-diethyl­pyridine-3-carboxamide-κ(2) n (1):o]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274867/
https://www.ncbi.nlm.nih.gov/pubmed/22346814
http://dx.doi.org/10.1107/S1600536812000025
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