Bis(10-meth­oxy­benzo[h]quinolinium) tetra­chloridozinc

In the title compound, (C(14)H(12)NO)(2)[ZnCl(4)], the benzo[h]quinolinium groups are approximately planar, with maximum deviations of 0.049 (8) and 0.056 (9) Å. The meth­oxy groups are stabilized by intra­molecular N—H⋯O hydrogen bonds. The structure also exhibits weak inter­molecular N—H⋯Cl hydrog...

Descripción completa

Detalles Bibliográficos
Autores principales: Dong, Zhenming, Liu, Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274869/
https://www.ncbi.nlm.nih.gov/pubmed/22346816
http://dx.doi.org/10.1107/S1600536811055462
_version_ 1782223123870908416
author Dong, Zhenming
Liu, Bo
author_facet Dong, Zhenming
Liu, Bo
author_sort Dong, Zhenming
collection PubMed
description In the title compound, (C(14)H(12)NO)(2)[ZnCl(4)], the benzo[h]quinolinium groups are approximately planar, with maximum deviations of 0.049 (8) and 0.056 (9) Å. The meth­oxy groups are stabilized by intra­molecular N—H⋯O hydrogen bonds. The structure also exhibits weak inter­molecular N—H⋯Cl hydrogen bonds between the cations and anions. π–π inter­actions are present between the pyridinium and benzene rings [centroid–centroid distances = 3.640 (4), 3.728 (5) and 3.628 (5) Å].
format Online
Article
Text
id pubmed-3274869
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32748692012-02-15 Bis(10-meth­oxy­benzo[h]quinolinium) tetra­chloridozinc Dong, Zhenming Liu, Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(14)H(12)NO)(2)[ZnCl(4)], the benzo[h]quinolinium groups are approximately planar, with maximum deviations of 0.049 (8) and 0.056 (9) Å. The meth­oxy groups are stabilized by intra­molecular N—H⋯O hydrogen bonds. The structure also exhibits weak inter­molecular N—H⋯Cl hydrogen bonds between the cations and anions. π–π inter­actions are present between the pyridinium and benzene rings [centroid–centroid distances = 3.640 (4), 3.728 (5) and 3.628 (5) Å]. International Union of Crystallography 2012-01-11 /pmc/articles/PMC3274869/ /pubmed/22346816 http://dx.doi.org/10.1107/S1600536811055462 Text en © Dong and Liu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dong, Zhenming
Liu, Bo
Bis(10-meth­oxy­benzo[h]quinolinium) tetra­chloridozinc
title Bis(10-meth­oxy­benzo[h]quinolinium) tetra­chloridozinc
title_full Bis(10-meth­oxy­benzo[h]quinolinium) tetra­chloridozinc
title_fullStr Bis(10-meth­oxy­benzo[h]quinolinium) tetra­chloridozinc
title_full_unstemmed Bis(10-meth­oxy­benzo[h]quinolinium) tetra­chloridozinc
title_short Bis(10-meth­oxy­benzo[h]quinolinium) tetra­chloridozinc
title_sort bis(10-meth­oxy­benzo[h]quinolinium) tetra­chloridozinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274869/
https://www.ncbi.nlm.nih.gov/pubmed/22346816
http://dx.doi.org/10.1107/S1600536811055462
work_keys_str_mv AT dongzhenming bis10methoxybenzohquinoliniumtetrachloridozinc
AT liubo bis10methoxybenzohquinoliniumtetrachloridozinc

Ejemplares similares