{(E)-4-Hy­droxy-N′-[phen­yl(pyridin-2-yl-κN)methyl­idene]benzohydrazide-κ(2) N′,O}bis­(nitrato-κ(2) O,O′)copper(II)

In the title compound, [Cu(NO(3))(2)(C(19)H(15)N(3)O(2))], the coordination geometry around the Cu(II) ion can be described as distorted square-pyramidal, with two N atoms and one O atom from an (E)-4-hy­droxy-N′-[phen­yl(pyridin-2-yl)methyl­ene]benzohydrazide ligand and one nitrate O atom in the ba...

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Detalles Bibliográficos
Autores principales: Bikas, Rahman, Sattari, Farhad, Notash, Behrouz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274870/
https://www.ncbi.nlm.nih.gov/pubmed/22346817
http://dx.doi.org/10.1107/S1600536811055772
Descripción
Sumario:In the title compound, [Cu(NO(3))(2)(C(19)H(15)N(3)O(2))], the coordination geometry around the Cu(II) ion can be described as distorted square-pyramidal, with two N atoms and one O atom from an (E)-4-hy­droxy-N′-[phen­yl(pyridin-2-yl)methyl­ene]benzohydrazide ligand and one nitrate O atom in the basal plane and one nitrate O atom at the apical site. The other two nitrate O atoms also bind to the Cu atom with long Cu—O distances [2.607 (4) and 2.853 (5) Å]. The crystal packing is stabilized by inter­molecular N—H⋯O and O—H⋯O hydrogen bonds.

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