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{(E)-4-Hydroxy-N′-[phenyl(pyridin-2-yl-κN)methylidene]benzohydrazide-κ(2) N′,O}bis(nitrato-κ(2) O,O′)copper(II)
In the title compound, [Cu(NO(3))(2)(C(19)H(15)N(3)O(2))], the coordination geometry around the Cu(II) ion can be described as distorted square-pyramidal, with two N atoms and one O atom from an (E)-4-hydroxy-N′-[phenyl(pyridin-2-yl)methylene]benzohydrazide ligand and one nitrate O atom in the ba...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274870/ https://www.ncbi.nlm.nih.gov/pubmed/22346817 http://dx.doi.org/10.1107/S1600536811055772 |
| _version_ | 1782223124103692288 |
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| author | Bikas, Rahman Sattari, Farhad Notash, Behrouz |
| author_facet | Bikas, Rahman Sattari, Farhad Notash, Behrouz |
| author_sort | Bikas, Rahman |
| collection | PubMed |
| description | In the title compound, [Cu(NO(3))(2)(C(19)H(15)N(3)O(2))], the coordination geometry around the Cu(II) ion can be described as distorted square-pyramidal, with two N atoms and one O atom from an (E)-4-hydroxy-N′-[phenyl(pyridin-2-yl)methylene]benzohydrazide ligand and one nitrate O atom in the basal plane and one nitrate O atom at the apical site. The other two nitrate O atoms also bind to the Cu atom with long Cu—O distances [2.607 (4) and 2.853 (5) Å]. The crystal packing is stabilized by intermolecular N—H⋯O and O—H⋯O hydrogen bonds. |
| format | Online Article Text |
| id | pubmed-3274870 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32748702012-02-15 {(E)-4-Hydroxy-N′-[phenyl(pyridin-2-yl-κN)methylidene]benzohydrazide-κ(2) N′,O}bis(nitrato-κ(2) O,O′)copper(II) Bikas, Rahman Sattari, Farhad Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(NO(3))(2)(C(19)H(15)N(3)O(2))], the coordination geometry around the Cu(II) ion can be described as distorted square-pyramidal, with two N atoms and one O atom from an (E)-4-hydroxy-N′-[phenyl(pyridin-2-yl)methylene]benzohydrazide ligand and one nitrate O atom in the basal plane and one nitrate O atom at the apical site. The other two nitrate O atoms also bind to the Cu atom with long Cu—O distances [2.607 (4) and 2.853 (5) Å]. The crystal packing is stabilized by intermolecular N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2012-01-11 /pmc/articles/PMC3274870/ /pubmed/22346817 http://dx.doi.org/10.1107/S1600536811055772 Text en © Bikas et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Bikas, Rahman Sattari, Farhad Notash, Behrouz {(E)-4-Hydroxy-N′-[phenyl(pyridin-2-yl-κN)methylidene]benzohydrazide-κ(2) N′,O}bis(nitrato-κ(2) O,O′)copper(II) |
| title | {(E)-4-Hydroxy-N′-[phenyl(pyridin-2-yl-κN)methylidene]benzohydrazide-κ(2)
N′,O}bis(nitrato-κ(2)
O,O′)copper(II) |
| title_full | {(E)-4-Hydroxy-N′-[phenyl(pyridin-2-yl-κN)methylidene]benzohydrazide-κ(2)
N′,O}bis(nitrato-κ(2)
O,O′)copper(II) |
| title_fullStr | {(E)-4-Hydroxy-N′-[phenyl(pyridin-2-yl-κN)methylidene]benzohydrazide-κ(2)
N′,O}bis(nitrato-κ(2)
O,O′)copper(II) |
| title_full_unstemmed | {(E)-4-Hydroxy-N′-[phenyl(pyridin-2-yl-κN)methylidene]benzohydrazide-κ(2)
N′,O}bis(nitrato-κ(2)
O,O′)copper(II) |
| title_short | {(E)-4-Hydroxy-N′-[phenyl(pyridin-2-yl-κN)methylidene]benzohydrazide-κ(2)
N′,O}bis(nitrato-κ(2)
O,O′)copper(II) |
| title_sort | {(e)-4-hydroxy-n′-[phenyl(pyridin-2-yl-κn)methylidene]benzohydrazide-κ(2)
n′,o}bis(nitrato-κ(2)
o,o′)copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274870/ https://www.ncbi.nlm.nih.gov/pubmed/22346817 http://dx.doi.org/10.1107/S1600536811055772 |
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