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Aqua[1,8-bis(pyridin-2-yl)-3,6-dithiaoctane-κ(4) N,S,S′,N′]copper(II) dinitrate acetonitrile monosolvate
In the title compound, [Cu(C(16)H(20)N(2)S(2))(H(2)O)](NO(3))(2)·CH(3)CN, the Cu(II) atom displays a distorted square-pyramidal coordination, in which a water molecule occupies the apical position and the basal plane is formed by two N atoms and two S atoms of a 1,8-bis(pyridin-2-yl)-3,6-dithiaoc...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274872/ https://www.ncbi.nlm.nih.gov/pubmed/22346819 http://dx.doi.org/10.1107/S1600536811056145 |
| _version_ | 1782223124574502912 |
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| author | Manzanera-Estrada, Mayra Flores-Alamo, Marcos Grevy M., Jean-Michel Ruiz-Azuara, Lena Ortiz-Frade, Luis |
| author_facet | Manzanera-Estrada, Mayra Flores-Alamo, Marcos Grevy M., Jean-Michel Ruiz-Azuara, Lena Ortiz-Frade, Luis |
| author_sort | Manzanera-Estrada, Mayra |
| collection | PubMed |
| description | In the title compound, [Cu(C(16)H(20)N(2)S(2))(H(2)O)](NO(3))(2)·CH(3)CN, the Cu(II) atom displays a distorted square-pyramidal coordination, in which a water molecule occupies the apical position and the basal plane is formed by two N atoms and two S atoms of a 1,8-bis(pyridin-2-yl)-3,6-dithiaoctane ligand. The crystal packing is stabilized by O—H⋯O and C—H⋯O hydrogen bonds. |
| format | Online Article Text |
| id | pubmed-3274872 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32748722012-02-15 Aqua[1,8-bis(pyridin-2-yl)-3,6-dithiaoctane-κ(4) N,S,S′,N′]copper(II) dinitrate acetonitrile monosolvate Manzanera-Estrada, Mayra Flores-Alamo, Marcos Grevy M., Jean-Michel Ruiz-Azuara, Lena Ortiz-Frade, Luis Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(16)H(20)N(2)S(2))(H(2)O)](NO(3))(2)·CH(3)CN, the Cu(II) atom displays a distorted square-pyramidal coordination, in which a water molecule occupies the apical position and the basal plane is formed by two N atoms and two S atoms of a 1,8-bis(pyridin-2-yl)-3,6-dithiaoctane ligand. The crystal packing is stabilized by O—H⋯O and C—H⋯O hydrogen bonds. International Union of Crystallography 2012-01-11 /pmc/articles/PMC3274872/ /pubmed/22346819 http://dx.doi.org/10.1107/S1600536811056145 Text en © Manzanera-Estrada et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Manzanera-Estrada, Mayra Flores-Alamo, Marcos Grevy M., Jean-Michel Ruiz-Azuara, Lena Ortiz-Frade, Luis Aqua[1,8-bis(pyridin-2-yl)-3,6-dithiaoctane-κ(4) N,S,S′,N′]copper(II) dinitrate acetonitrile monosolvate |
| title | Aqua[1,8-bis(pyridin-2-yl)-3,6-dithiaoctane-κ(4)
N,S,S′,N′]copper(II) dinitrate acetonitrile monosolvate |
| title_full | Aqua[1,8-bis(pyridin-2-yl)-3,6-dithiaoctane-κ(4)
N,S,S′,N′]copper(II) dinitrate acetonitrile monosolvate |
| title_fullStr | Aqua[1,8-bis(pyridin-2-yl)-3,6-dithiaoctane-κ(4)
N,S,S′,N′]copper(II) dinitrate acetonitrile monosolvate |
| title_full_unstemmed | Aqua[1,8-bis(pyridin-2-yl)-3,6-dithiaoctane-κ(4)
N,S,S′,N′]copper(II) dinitrate acetonitrile monosolvate |
| title_short | Aqua[1,8-bis(pyridin-2-yl)-3,6-dithiaoctane-κ(4)
N,S,S′,N′]copper(II) dinitrate acetonitrile monosolvate |
| title_sort | aqua[1,8-bis(pyridin-2-yl)-3,6-dithiaoctane-κ(4)
n,s,s′,n′]copper(ii) dinitrate acetonitrile monosolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274872/ https://www.ncbi.nlm.nih.gov/pubmed/22346819 http://dx.doi.org/10.1107/S1600536811056145 |
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