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catena-Poly[[bis(methanol-κO)bis(thiocyanato-κN)cobalt(II)]-μ-1,3-bis(pyridin-4-yl)propane-κ(2) N,N′]
The asymmetric unit of the title compound, [Co(NCS)(2)(C(13)H(14)N(2))(CH(3)OH)(2)], consists of one cobalt(II) cation located on a center of inversion, one half of a 1,3-bis(pyridin-4-yl)propane ligand located on a twofold rotation axis, as well as one thiocyanate anion and one methanol molecule...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274874/ https://www.ncbi.nlm.nih.gov/pubmed/22346821 http://dx.doi.org/10.1107/S1600536812000499 |
Sumario: | The asymmetric unit of the title compound, [Co(NCS)(2)(C(13)H(14)N(2))(CH(3)OH)(2)], consists of one cobalt(II) cation located on a center of inversion, one half of a 1,3-bis(pyridin-4-yl)propane ligand located on a twofold rotation axis, as well as one thiocyanate anion and one methanol molecule in general positions. The cobalt(II) cation is coordinated by two terminal N-bonded thiocyanate anions and two N-bonded 1,3-bis(pyridin-4-yl)propane ligands, as well as two O atoms of methanol molecules in a slightly distorted octahedral coordination mode. Adjacent cations are connected into chains parallel to [10[Image: see text]] by the bridging 1,3-bis(pyridin-4-yl)propane ligands. These chains are connected through intermolecular O—H⋯S hydrogen bonds between the methanol hydroxy group and the terminal S atom of the thiocyanate anion. |
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