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catena-Poly[[bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)]-μ-1,3-bis­(pyridin-4-yl)propane-κ(2) N,N′]

The asymmetric unit of the title compound, [Co(NCS)(2)(C(13)H(14)N(2))(CH(3)OH)(2)], consists of one cobalt(II) cation located on a center of inversion, one half of a 1,3-bis­(pyridin-4-yl)propane ligand located on a twofold rotation axis, as well as one thio­cyanate anion and one methanol mol­ecule...

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Detalles Bibliográficos
Autores principales: Wöhlert, Susanne, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274874/
https://www.ncbi.nlm.nih.gov/pubmed/22346821
http://dx.doi.org/10.1107/S1600536812000499
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author Wöhlert, Susanne
Näther, Christian
author_facet Wöhlert, Susanne
Näther, Christian
author_sort Wöhlert, Susanne
collection PubMed
description The asymmetric unit of the title compound, [Co(NCS)(2)(C(13)H(14)N(2))(CH(3)OH)(2)], consists of one cobalt(II) cation located on a center of inversion, one half of a 1,3-bis­(pyridin-4-yl)propane ligand located on a twofold rotation axis, as well as one thio­cyanate anion and one methanol mol­ecule in general positions. The cobalt(II) cation is coordinated by two terminal N-bonded thio­cyanate anions and two N-bonded 1,3-bis­(pyridin-4-yl)propane ligands, as well as two O atoms of methanol mol­ecules in a slightly distorted octa­hedral coordination mode. Adjacent cations are connected into chains parallel to [10[Image: see text]] by the bridging 1,3-bis­(pyridin-4-yl)propane ligands. These chains are connected through inter­molecular O—H⋯S hydrogen bonds between the methanol hy­droxy group and the terminal S atom of the thio­cyanate anion.
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spelling pubmed-32748742012-02-15 catena-Poly[[bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)]-μ-1,3-bis­(pyridin-4-yl)propane-κ(2) N,N′] Wöhlert, Susanne Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Co(NCS)(2)(C(13)H(14)N(2))(CH(3)OH)(2)], consists of one cobalt(II) cation located on a center of inversion, one half of a 1,3-bis­(pyridin-4-yl)propane ligand located on a twofold rotation axis, as well as one thio­cyanate anion and one methanol mol­ecule in general positions. The cobalt(II) cation is coordinated by two terminal N-bonded thio­cyanate anions and two N-bonded 1,3-bis­(pyridin-4-yl)propane ligands, as well as two O atoms of methanol mol­ecules in a slightly distorted octa­hedral coordination mode. Adjacent cations are connected into chains parallel to [10[Image: see text]] by the bridging 1,3-bis­(pyridin-4-yl)propane ligands. These chains are connected through inter­molecular O—H⋯S hydrogen bonds between the methanol hy­droxy group and the terminal S atom of the thio­cyanate anion. International Union of Crystallography 2012-01-11 /pmc/articles/PMC3274874/ /pubmed/22346821 http://dx.doi.org/10.1107/S1600536812000499 Text en © Wöhlert and Näther 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wöhlert, Susanne
Näther, Christian
catena-Poly[[bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)]-μ-1,3-bis­(pyridin-4-yl)propane-κ(2) N,N′]
title catena-Poly[[bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)]-μ-1,3-bis­(pyridin-4-yl)propane-κ(2) N,N′]
title_full catena-Poly[[bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)]-μ-1,3-bis­(pyridin-4-yl)propane-κ(2) N,N′]
title_fullStr catena-Poly[[bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)]-μ-1,3-bis­(pyridin-4-yl)propane-κ(2) N,N′]
title_full_unstemmed catena-Poly[[bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)]-μ-1,3-bis­(pyridin-4-yl)propane-κ(2) N,N′]
title_short catena-Poly[[bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)]-μ-1,3-bis­(pyridin-4-yl)propane-κ(2) N,N′]
title_sort catena-poly[[bis­(methanol-κo)bis­(thio­cyanato-κn)cobalt(ii)]-μ-1,3-bis­(pyridin-4-yl)propane-κ(2) n,n′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274874/
https://www.ncbi.nlm.nih.gov/pubmed/22346821
http://dx.doi.org/10.1107/S1600536812000499
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