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Diaqua­bis­{1-[(1H-benzimidazol-2-yl)meth­yl]-1H-1,2,4-triazole-κN (4)}bis­(2,4,5-tricarb­oxy­benzoato-κO (1))cadmium dihydrate

In the title complex, [Cd(C(10)H(5)O(8))(2)(C(10)H(9)N(5))(2)(H(2)O)(2)]·2H(2)O, the Cd(II) ion lies on an inversion center and is coordinated by two N atoms from two symmetry-related 1-[(1H-benzimidazol-2-yl)meth­yl]-1H-1,2,4-triazole ligands and two O atoms from two monodeprotonated 2,4,5-tricarb­...

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Detalles Bibliográficos
Autores principales: Zhao, Lei, Liu, Bingtao, Jin, Guanghua, Meng, Xiangru
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274875/
https://www.ncbi.nlm.nih.gov/pubmed/22346822
http://dx.doi.org/10.1107/S1600536812000384
Descripción
Sumario:In the title complex, [Cd(C(10)H(5)O(8))(2)(C(10)H(9)N(5))(2)(H(2)O)(2)]·2H(2)O, the Cd(II) ion lies on an inversion center and is coordinated by two N atoms from two symmetry-related 1-[(1H-benzimidazol-2-yl)meth­yl]-1H-1,2,4-triazole ligands and two O atoms from two monodeprotonated 2,4,5-tricarb­oxy­benzoate anions in equatorial positions and by two water O atoms in axial positions, leading to a distorted octa­hedral environment. In the crystal, complex mol­ecules and solvent water mol­ecules are linked through inter­molecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds into a three-dimensional network. Intra­molecular O—H⋯O hydrogen bonds are also present.