Cargando…

Diaqua­bis­{1-[(1H-benzimidazol-2-yl)meth­yl]-1H-1,2,4-triazole-κN (4)}bis­(2,4,5-tricarb­oxy­benzoato-κO (1))cadmium dihydrate

In the title complex, [Cd(C(10)H(5)O(8))(2)(C(10)H(9)N(5))(2)(H(2)O)(2)]·2H(2)O, the Cd(II) ion lies on an inversion center and is coordinated by two N atoms from two symmetry-related 1-[(1H-benzimidazol-2-yl)meth­yl]-1H-1,2,4-triazole ligands and two O atoms from two monodeprotonated 2,4,5-tricarb­...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhao, Lei, Liu, Bingtao, Jin, Guanghua, Meng, Xiangru
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274875/
https://www.ncbi.nlm.nih.gov/pubmed/22346822
http://dx.doi.org/10.1107/S1600536812000384
_version_ 1782223125272854528
author Zhao, Lei
Liu, Bingtao
Jin, Guanghua
Meng, Xiangru
author_facet Zhao, Lei
Liu, Bingtao
Jin, Guanghua
Meng, Xiangru
author_sort Zhao, Lei
collection PubMed
description In the title complex, [Cd(C(10)H(5)O(8))(2)(C(10)H(9)N(5))(2)(H(2)O)(2)]·2H(2)O, the Cd(II) ion lies on an inversion center and is coordinated by two N atoms from two symmetry-related 1-[(1H-benzimidazol-2-yl)meth­yl]-1H-1,2,4-triazole ligands and two O atoms from two monodeprotonated 2,4,5-tricarb­oxy­benzoate anions in equatorial positions and by two water O atoms in axial positions, leading to a distorted octa­hedral environment. In the crystal, complex mol­ecules and solvent water mol­ecules are linked through inter­molecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds into a three-dimensional network. Intra­molecular O—H⋯O hydrogen bonds are also present.
format Online
Article
Text
id pubmed-3274875
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32748752012-02-15 Diaqua­bis­{1-[(1H-benzimidazol-2-yl)meth­yl]-1H-1,2,4-triazole-κN (4)}bis­(2,4,5-tricarb­oxy­benzoato-κO (1))cadmium dihydrate Zhao, Lei Liu, Bingtao Jin, Guanghua Meng, Xiangru Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(C(10)H(5)O(8))(2)(C(10)H(9)N(5))(2)(H(2)O)(2)]·2H(2)O, the Cd(II) ion lies on an inversion center and is coordinated by two N atoms from two symmetry-related 1-[(1H-benzimidazol-2-yl)meth­yl]-1H-1,2,4-triazole ligands and two O atoms from two monodeprotonated 2,4,5-tricarb­oxy­benzoate anions in equatorial positions and by two water O atoms in axial positions, leading to a distorted octa­hedral environment. In the crystal, complex mol­ecules and solvent water mol­ecules are linked through inter­molecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds into a three-dimensional network. Intra­molecular O—H⋯O hydrogen bonds are also present. International Union of Crystallography 2012-01-11 /pmc/articles/PMC3274875/ /pubmed/22346822 http://dx.doi.org/10.1107/S1600536812000384 Text en © Zhao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Lei
Liu, Bingtao
Jin, Guanghua
Meng, Xiangru
Diaqua­bis­{1-[(1H-benzimidazol-2-yl)meth­yl]-1H-1,2,4-triazole-κN (4)}bis­(2,4,5-tricarb­oxy­benzoato-κO (1))cadmium dihydrate
title Diaqua­bis­{1-[(1H-benzimidazol-2-yl)meth­yl]-1H-1,2,4-triazole-κN (4)}bis­(2,4,5-tricarb­oxy­benzoato-κO (1))cadmium dihydrate
title_full Diaqua­bis­{1-[(1H-benzimidazol-2-yl)meth­yl]-1H-1,2,4-triazole-κN (4)}bis­(2,4,5-tricarb­oxy­benzoato-κO (1))cadmium dihydrate
title_fullStr Diaqua­bis­{1-[(1H-benzimidazol-2-yl)meth­yl]-1H-1,2,4-triazole-κN (4)}bis­(2,4,5-tricarb­oxy­benzoato-κO (1))cadmium dihydrate
title_full_unstemmed Diaqua­bis­{1-[(1H-benzimidazol-2-yl)meth­yl]-1H-1,2,4-triazole-κN (4)}bis­(2,4,5-tricarb­oxy­benzoato-κO (1))cadmium dihydrate
title_short Diaqua­bis­{1-[(1H-benzimidazol-2-yl)meth­yl]-1H-1,2,4-triazole-κN (4)}bis­(2,4,5-tricarb­oxy­benzoato-κO (1))cadmium dihydrate
title_sort diaqua­bis­{1-[(1h-benzimidazol-2-yl)meth­yl]-1h-1,2,4-triazole-κn (4)}bis­(2,4,5-tricarb­oxy­benzoato-κo (1))cadmium dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274875/
https://www.ncbi.nlm.nih.gov/pubmed/22346822
http://dx.doi.org/10.1107/S1600536812000384
work_keys_str_mv AT zhaolei diaquabis11hbenzimidazol2ylmethyl1h124triazolekn4bis245tricarboxybenzoatoko1cadmiumdihydrate
AT liubingtao diaquabis11hbenzimidazol2ylmethyl1h124triazolekn4bis245tricarboxybenzoatoko1cadmiumdihydrate
AT jinguanghua diaquabis11hbenzimidazol2ylmethyl1h124triazolekn4bis245tricarboxybenzoatoko1cadmiumdihydrate
AT mengxiangru diaquabis11hbenzimidazol2ylmethyl1h124triazolekn4bis245tricarboxybenzoatoko1cadmiumdihydrate