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Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole-κN (4)}bis(2,4,5-tricarboxybenzoato-κO (1))cadmium dihydrate
In the title complex, [Cd(C(10)H(5)O(8))(2)(C(10)H(9)N(5))(2)(H(2)O)(2)]·2H(2)O, the Cd(II) ion lies on an inversion center and is coordinated by two N atoms from two symmetry-related 1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole ligands and two O atoms from two monodeprotonated 2,4,5-tricarb...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274875/ https://www.ncbi.nlm.nih.gov/pubmed/22346822 http://dx.doi.org/10.1107/S1600536812000384 |
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author | Zhao, Lei Liu, Bingtao Jin, Guanghua Meng, Xiangru |
author_facet | Zhao, Lei Liu, Bingtao Jin, Guanghua Meng, Xiangru |
author_sort | Zhao, Lei |
collection | PubMed |
description | In the title complex, [Cd(C(10)H(5)O(8))(2)(C(10)H(9)N(5))(2)(H(2)O)(2)]·2H(2)O, the Cd(II) ion lies on an inversion center and is coordinated by two N atoms from two symmetry-related 1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole ligands and two O atoms from two monodeprotonated 2,4,5-tricarboxybenzoate anions in equatorial positions and by two water O atoms in axial positions, leading to a distorted octahedral environment. In the crystal, complex molecules and solvent water molecules are linked through intermolecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds into a three-dimensional network. Intramolecular O—H⋯O hydrogen bonds are also present. |
format | Online Article Text |
id | pubmed-3274875 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32748752012-02-15 Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole-κN (4)}bis(2,4,5-tricarboxybenzoato-κO (1))cadmium dihydrate Zhao, Lei Liu, Bingtao Jin, Guanghua Meng, Xiangru Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(C(10)H(5)O(8))(2)(C(10)H(9)N(5))(2)(H(2)O)(2)]·2H(2)O, the Cd(II) ion lies on an inversion center and is coordinated by two N atoms from two symmetry-related 1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole ligands and two O atoms from two monodeprotonated 2,4,5-tricarboxybenzoate anions in equatorial positions and by two water O atoms in axial positions, leading to a distorted octahedral environment. In the crystal, complex molecules and solvent water molecules are linked through intermolecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds into a three-dimensional network. Intramolecular O—H⋯O hydrogen bonds are also present. International Union of Crystallography 2012-01-11 /pmc/articles/PMC3274875/ /pubmed/22346822 http://dx.doi.org/10.1107/S1600536812000384 Text en © Zhao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhao, Lei Liu, Bingtao Jin, Guanghua Meng, Xiangru Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole-κN (4)}bis(2,4,5-tricarboxybenzoato-κO (1))cadmium dihydrate |
title | Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole-κN
(4)}bis(2,4,5-tricarboxybenzoato-κO
(1))cadmium dihydrate |
title_full | Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole-κN
(4)}bis(2,4,5-tricarboxybenzoato-κO
(1))cadmium dihydrate |
title_fullStr | Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole-κN
(4)}bis(2,4,5-tricarboxybenzoato-κO
(1))cadmium dihydrate |
title_full_unstemmed | Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole-κN
(4)}bis(2,4,5-tricarboxybenzoato-κO
(1))cadmium dihydrate |
title_short | Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-1,2,4-triazole-κN
(4)}bis(2,4,5-tricarboxybenzoato-κO
(1))cadmium dihydrate |
title_sort | diaquabis{1-[(1h-benzimidazol-2-yl)methyl]-1h-1,2,4-triazole-κn
(4)}bis(2,4,5-tricarboxybenzoato-κo
(1))cadmium dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274875/ https://www.ncbi.nlm.nih.gov/pubmed/22346822 http://dx.doi.org/10.1107/S1600536812000384 |
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