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Bis{μ-2-[(dimethyl­amino)­meth­yl]benzene­tellurolato}bis­[chlorido­palladium(II)] dichloro­methane hemisolvate

The asymmetric unit of the title compound, [Pd(2)(C(9)H(12)NTe)(2)Cl(2)]·0.5CH(2)Cl(2), contains two half-mol­ecules, each lying on a twofold rotation axis; each mol­ecule is chiral and of the same enanti­omer. This is only possible as the mol­ecule has a hinged cis arrangement about the Pd(2+) coor...

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Detalles Bibliográficos
Autores principales: Butcher, Ray J., Chakravorty, Tapash, Singh, Harkesh B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274876/
https://www.ncbi.nlm.nih.gov/pubmed/22346823
http://dx.doi.org/10.1107/S1600536812000104
Descripción
Sumario:The asymmetric unit of the title compound, [Pd(2)(C(9)H(12)NTe)(2)Cl(2)]·0.5CH(2)Cl(2), contains two half-mol­ecules, each lying on a twofold rotation axis; each mol­ecule is chiral and of the same enanti­omer. This is only possible as the mol­ecule has a hinged cis arrangement about the Pd(2+) coordination spheres. For this hinged dimeric structure, the angles between the two coordination planes in each mol­ecule are 21.59 (4) and 22.10 (4)°. This hinged cis arrangement also allows the two mol­ecules to form pairs linked by secondary inter­actions between the Pd and Te atoms of an adjoining mol­ecule, leading to a tetra­meric overall structure. C—H⋯Cl inter­actions consolidate the crystal packing.