Bis{μ-2-[(dimethyl­amino)­meth­yl]benzene­tellurolato}bis­[chlorido­palladium(II)] dichloro­methane hemisolvate

The asymmetric unit of the title compound, [Pd(2)(C(9)H(12)NTe)(2)Cl(2)]·0.5CH(2)Cl(2), contains two half-mol­ecules, each lying on a twofold rotation axis; each mol­ecule is chiral and of the same enanti­omer. This is only possible as the mol­ecule has a hinged cis arrangement about the Pd(2+) coor...

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Detalles Bibliográficos
Autores principales: Butcher, Ray J., Chakravorty, Tapash, Singh, Harkesh B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274876/
https://www.ncbi.nlm.nih.gov/pubmed/22346823
http://dx.doi.org/10.1107/S1600536812000104
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author Butcher, Ray J.
Chakravorty, Tapash
Singh, Harkesh B.
author_facet Butcher, Ray J.
Chakravorty, Tapash
Singh, Harkesh B.
author_sort Butcher, Ray J.
collection PubMed
description The asymmetric unit of the title compound, [Pd(2)(C(9)H(12)NTe)(2)Cl(2)]·0.5CH(2)Cl(2), contains two half-mol­ecules, each lying on a twofold rotation axis; each mol­ecule is chiral and of the same enanti­omer. This is only possible as the mol­ecule has a hinged cis arrangement about the Pd(2+) coordination spheres. For this hinged dimeric structure, the angles between the two coordination planes in each mol­ecule are 21.59 (4) and 22.10 (4)°. This hinged cis arrangement also allows the two mol­ecules to form pairs linked by secondary inter­actions between the Pd and Te atoms of an adjoining mol­ecule, leading to a tetra­meric overall structure. C—H⋯Cl inter­actions consolidate the crystal packing.
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spelling pubmed-32748762012-02-15 Bis{μ-2-[(dimethyl­amino)­meth­yl]benzene­tellurolato}bis­[chlorido­palladium(II)] dichloro­methane hemisolvate Butcher, Ray J. Chakravorty, Tapash Singh, Harkesh B. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Pd(2)(C(9)H(12)NTe)(2)Cl(2)]·0.5CH(2)Cl(2), contains two half-mol­ecules, each lying on a twofold rotation axis; each mol­ecule is chiral and of the same enanti­omer. This is only possible as the mol­ecule has a hinged cis arrangement about the Pd(2+) coordination spheres. For this hinged dimeric structure, the angles between the two coordination planes in each mol­ecule are 21.59 (4) and 22.10 (4)°. This hinged cis arrangement also allows the two mol­ecules to form pairs linked by secondary inter­actions between the Pd and Te atoms of an adjoining mol­ecule, leading to a tetra­meric overall structure. C—H⋯Cl inter­actions consolidate the crystal packing. International Union of Crystallography 2012-01-11 /pmc/articles/PMC3274876/ /pubmed/22346823 http://dx.doi.org/10.1107/S1600536812000104 Text en © Butcher et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Butcher, Ray J.
Chakravorty, Tapash
Singh, Harkesh B.
Bis{μ-2-[(dimethyl­amino)­meth­yl]benzene­tellurolato}bis­[chlorido­palladium(II)] dichloro­methane hemisolvate
title Bis{μ-2-[(dimethyl­amino)­meth­yl]benzene­tellurolato}bis­[chlorido­palladium(II)] dichloro­methane hemisolvate
title_full Bis{μ-2-[(dimethyl­amino)­meth­yl]benzene­tellurolato}bis­[chlorido­palladium(II)] dichloro­methane hemisolvate
title_fullStr Bis{μ-2-[(dimethyl­amino)­meth­yl]benzene­tellurolato}bis­[chlorido­palladium(II)] dichloro­methane hemisolvate
title_full_unstemmed Bis{μ-2-[(dimethyl­amino)­meth­yl]benzene­tellurolato}bis­[chlorido­palladium(II)] dichloro­methane hemisolvate
title_short Bis{μ-2-[(dimethyl­amino)­meth­yl]benzene­tellurolato}bis­[chlorido­palladium(II)] dichloro­methane hemisolvate
title_sort bis{μ-2-[(dimethyl­amino)­meth­yl]benzene­tellurolato}bis­[chlorido­palladium(ii)] dichloro­methane hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274876/
https://www.ncbi.nlm.nih.gov/pubmed/22346823
http://dx.doi.org/10.1107/S1600536812000104
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AT singhharkeshb bism2dimethylaminomethylbenzenetellurolatobischloridopalladiumiidichloromethanehemisolvate

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