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trans-Dichloridobis(quinoline-κN)palladium(II)

In the title complex, [PdCl(2)(C(9)H(7)N)(2)], the Pd(II) ion is four-coordinated in an essentially square-planar environment defined by two N atoms from two quinoline ligands and two Cl(−) anions. The Pd atom is located on an inversion centre, and thus the asymmetric unit contains one half of the c...

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Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274877/
https://www.ncbi.nlm.nih.gov/pubmed/22346824
http://dx.doi.org/10.1107/S1600536811055954
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description In the title complex, [PdCl(2)(C(9)H(7)N)(2)], the Pd(II) ion is four-coordinated in an essentially square-planar environment defined by two N atoms from two quinoline ligands and two Cl(−) anions. The Pd atom is located on an inversion centre, and thus the asymmetric unit contains one half of the complex; the PdN(2)Cl(2) unit is exactly planar. The dihedral angle between the PdN(2)Cl(2) unit and quinoline ligand is 85.63 (8)°. In the crystal, the complex mol­ecules are stacked into columns along the b axis. In the columns, several inter­molecular π–π inter­actions between the six-membered rings are present, the shortest ring centroid–centroid distance being 3.764 (3) Å between pyridine rings.
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spelling pubmed-32748772012-02-15 trans-Dichloridobis(quinoline-κN)palladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PdCl(2)(C(9)H(7)N)(2)], the Pd(II) ion is four-coordinated in an essentially square-planar environment defined by two N atoms from two quinoline ligands and two Cl(−) anions. The Pd atom is located on an inversion centre, and thus the asymmetric unit contains one half of the complex; the PdN(2)Cl(2) unit is exactly planar. The dihedral angle between the PdN(2)Cl(2) unit and quinoline ligand is 85.63 (8)°. In the crystal, the complex mol­ecules are stacked into columns along the b axis. In the columns, several inter­molecular π–π inter­actions between the six-membered rings are present, the shortest ring centroid–centroid distance being 3.764 (3) Å between pyridine rings. International Union of Crystallography 2012-01-14 /pmc/articles/PMC3274877/ /pubmed/22346824 http://dx.doi.org/10.1107/S1600536811055954 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
trans-Dichloridobis(quinoline-κN)palladium(II)
title trans-Dichloridobis(quinoline-κN)palladium(II)
title_full trans-Dichloridobis(quinoline-κN)palladium(II)
title_fullStr trans-Dichloridobis(quinoline-κN)palladium(II)
title_full_unstemmed trans-Dichloridobis(quinoline-κN)palladium(II)
title_short trans-Dichloridobis(quinoline-κN)palladium(II)
title_sort trans-dichloridobis(quinoline-κn)palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274877/
https://www.ncbi.nlm.nih.gov/pubmed/22346824
http://dx.doi.org/10.1107/S1600536811055954
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