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trans-Dichloridobis(quinoline-κN)palladium(II)
In the title complex, [PdCl(2)(C(9)H(7)N)(2)], the Pd(II) ion is four-coordinated in an essentially square-planar environment defined by two N atoms from two quinoline ligands and two Cl(−) anions. The Pd atom is located on an inversion centre, and thus the asymmetric unit contains one half of the c...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274877/ https://www.ncbi.nlm.nih.gov/pubmed/22346824 http://dx.doi.org/10.1107/S1600536811055954 |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | In the title complex, [PdCl(2)(C(9)H(7)N)(2)], the Pd(II) ion is four-coordinated in an essentially square-planar environment defined by two N atoms from two quinoline ligands and two Cl(−) anions. The Pd atom is located on an inversion centre, and thus the asymmetric unit contains one half of the complex; the PdN(2)Cl(2) unit is exactly planar. The dihedral angle between the PdN(2)Cl(2) unit and quinoline ligand is 85.63 (8)°. In the crystal, the complex molecules are stacked into columns along the b axis. In the columns, several intermolecular π–π interactions between the six-membered rings are present, the shortest ring centroid–centroid distance being 3.764 (3) Å between pyridine rings. |
format | Online Article Text |
id | pubmed-3274877 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32748772012-02-15 trans-Dichloridobis(quinoline-κN)palladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PdCl(2)(C(9)H(7)N)(2)], the Pd(II) ion is four-coordinated in an essentially square-planar environment defined by two N atoms from two quinoline ligands and two Cl(−) anions. The Pd atom is located on an inversion centre, and thus the asymmetric unit contains one half of the complex; the PdN(2)Cl(2) unit is exactly planar. The dihedral angle between the PdN(2)Cl(2) unit and quinoline ligand is 85.63 (8)°. In the crystal, the complex molecules are stacked into columns along the b axis. In the columns, several intermolecular π–π interactions between the six-membered rings are present, the shortest ring centroid–centroid distance being 3.764 (3) Å between pyridine rings. International Union of Crystallography 2012-01-14 /pmc/articles/PMC3274877/ /pubmed/22346824 http://dx.doi.org/10.1107/S1600536811055954 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang trans-Dichloridobis(quinoline-κN)palladium(II) |
title |
trans-Dichloridobis(quinoline-κN)palladium(II) |
title_full |
trans-Dichloridobis(quinoline-κN)palladium(II) |
title_fullStr |
trans-Dichloridobis(quinoline-κN)palladium(II) |
title_full_unstemmed |
trans-Dichloridobis(quinoline-κN)palladium(II) |
title_short |
trans-Dichloridobis(quinoline-κN)palladium(II) |
title_sort | trans-dichloridobis(quinoline-κn)palladium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274877/ https://www.ncbi.nlm.nih.gov/pubmed/22346824 http://dx.doi.org/10.1107/S1600536811055954 |
work_keys_str_mv | AT hakwang transdichloridobisquinolineknpalladiumii |