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(2,3-Di-2-pyridyl­pyrazine-κ(2) N (2),N (3))bis­(thio­cyanato-κS)palladium(II)

The Pd(II) ion in the title complex, [Pd(NCS)(2)(C(14)H(10)N(4))], is four-coordinated in a distorted square-planar environment by the two pyridine N atoms of the chelating 2,3-di-2-pyridyl­pyrazine (dpp) ligand and two S atoms from two thio­cyanate anions. The pyridine rings are considerably inclin...

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Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274878/
https://www.ncbi.nlm.nih.gov/pubmed/22346825
http://dx.doi.org/10.1107/S1600536812000980
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The Pd(II) ion in the title complex, [Pd(NCS)(2)(C(14)H(10)N(4))], is four-coordinated in a distorted square-planar environment by the two pyridine N atoms of the chelating 2,3-di-2-pyridyl­pyrazine (dpp) ligand and two S atoms from two thio­cyanate anions. The pyridine rings are considerably inclined to the least-squares plane of the PdS(2)N(2) unit [maximum deviation = 0.027 (1) Å], making dihedral angles of 70.3 (2) and 69.2 (1)°. The pyrazine ring is almost perpendicular to the PdS(2)N(2) plane, with a dihedral angle of 86.3 (1)°. The thio­cyanate ligands are located on opposite sides of the PdS(2)N(2) unit plane and are almost linear [N—C—S angles = 177.8 (6) and 178.9 (6)°]. The complex mol­ecules are stacked in columns along the b axis and are connected by inter­molecular C—H⋯N hydrogen bonds, forming chains along the a axis.
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spelling pubmed-32748782012-02-15 (2,3-Di-2-pyridyl­pyrazine-κ(2) N (2),N (3))bis­(thio­cyanato-κS)palladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pd(II) ion in the title complex, [Pd(NCS)(2)(C(14)H(10)N(4))], is four-coordinated in a distorted square-planar environment by the two pyridine N atoms of the chelating 2,3-di-2-pyridyl­pyrazine (dpp) ligand and two S atoms from two thio­cyanate anions. The pyridine rings are considerably inclined to the least-squares plane of the PdS(2)N(2) unit [maximum deviation = 0.027 (1) Å], making dihedral angles of 70.3 (2) and 69.2 (1)°. The pyrazine ring is almost perpendicular to the PdS(2)N(2) plane, with a dihedral angle of 86.3 (1)°. The thio­cyanate ligands are located on opposite sides of the PdS(2)N(2) unit plane and are almost linear [N—C—S angles = 177.8 (6) and 178.9 (6)°]. The complex mol­ecules are stacked in columns along the b axis and are connected by inter­molecular C—H⋯N hydrogen bonds, forming chains along the a axis. International Union of Crystallography 2012-01-14 /pmc/articles/PMC3274878/ /pubmed/22346825 http://dx.doi.org/10.1107/S1600536812000980 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
(2,3-Di-2-pyridyl­pyrazine-κ(2) N (2),N (3))bis­(thio­cyanato-κS)palladium(II)
title (2,3-Di-2-pyridyl­pyrazine-κ(2) N (2),N (3))bis­(thio­cyanato-κS)palladium(II)
title_full (2,3-Di-2-pyridyl­pyrazine-κ(2) N (2),N (3))bis­(thio­cyanato-κS)palladium(II)
title_fullStr (2,3-Di-2-pyridyl­pyrazine-κ(2) N (2),N (3))bis­(thio­cyanato-κS)palladium(II)
title_full_unstemmed (2,3-Di-2-pyridyl­pyrazine-κ(2) N (2),N (3))bis­(thio­cyanato-κS)palladium(II)
title_short (2,3-Di-2-pyridyl­pyrazine-κ(2) N (2),N (3))bis­(thio­cyanato-κS)palladium(II)
title_sort (2,3-di-2-pyridyl­pyrazine-κ(2) n (2),n (3))bis­(thio­cyanato-κs)palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274878/
https://www.ncbi.nlm.nih.gov/pubmed/22346825
http://dx.doi.org/10.1107/S1600536812000980
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