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(2,3-Di-2-pyridylpyrazine-κ(2) N (2),N (3))bis(thiocyanato-κS)palladium(II)
The Pd(II) ion in the title complex, [Pd(NCS)(2)(C(14)H(10)N(4))], is four-coordinated in a distorted square-planar environment by the two pyridine N atoms of the chelating 2,3-di-2-pyridylpyrazine (dpp) ligand and two S atoms from two thiocyanate anions. The pyridine rings are considerably inclin...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274878/ https://www.ncbi.nlm.nih.gov/pubmed/22346825 http://dx.doi.org/10.1107/S1600536812000980 |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | The Pd(II) ion in the title complex, [Pd(NCS)(2)(C(14)H(10)N(4))], is four-coordinated in a distorted square-planar environment by the two pyridine N atoms of the chelating 2,3-di-2-pyridylpyrazine (dpp) ligand and two S atoms from two thiocyanate anions. The pyridine rings are considerably inclined to the least-squares plane of the PdS(2)N(2) unit [maximum deviation = 0.027 (1) Å], making dihedral angles of 70.3 (2) and 69.2 (1)°. The pyrazine ring is almost perpendicular to the PdS(2)N(2) plane, with a dihedral angle of 86.3 (1)°. The thiocyanate ligands are located on opposite sides of the PdS(2)N(2) unit plane and are almost linear [N—C—S angles = 177.8 (6) and 178.9 (6)°]. The complex molecules are stacked in columns along the b axis and are connected by intermolecular C—H⋯N hydrogen bonds, forming chains along the a axis. |
format | Online Article Text |
id | pubmed-3274878 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32748782012-02-15 (2,3-Di-2-pyridylpyrazine-κ(2) N (2),N (3))bis(thiocyanato-κS)palladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pd(II) ion in the title complex, [Pd(NCS)(2)(C(14)H(10)N(4))], is four-coordinated in a distorted square-planar environment by the two pyridine N atoms of the chelating 2,3-di-2-pyridylpyrazine (dpp) ligand and two S atoms from two thiocyanate anions. The pyridine rings are considerably inclined to the least-squares plane of the PdS(2)N(2) unit [maximum deviation = 0.027 (1) Å], making dihedral angles of 70.3 (2) and 69.2 (1)°. The pyrazine ring is almost perpendicular to the PdS(2)N(2) plane, with a dihedral angle of 86.3 (1)°. The thiocyanate ligands are located on opposite sides of the PdS(2)N(2) unit plane and are almost linear [N—C—S angles = 177.8 (6) and 178.9 (6)°]. The complex molecules are stacked in columns along the b axis and are connected by intermolecular C—H⋯N hydrogen bonds, forming chains along the a axis. International Union of Crystallography 2012-01-14 /pmc/articles/PMC3274878/ /pubmed/22346825 http://dx.doi.org/10.1107/S1600536812000980 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang (2,3-Di-2-pyridylpyrazine-κ(2) N (2),N (3))bis(thiocyanato-κS)palladium(II) |
title | (2,3-Di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))bis(thiocyanato-κS)palladium(II) |
title_full | (2,3-Di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))bis(thiocyanato-κS)palladium(II) |
title_fullStr | (2,3-Di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))bis(thiocyanato-κS)palladium(II) |
title_full_unstemmed | (2,3-Di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))bis(thiocyanato-κS)palladium(II) |
title_short | (2,3-Di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))bis(thiocyanato-κS)palladium(II) |
title_sort | (2,3-di-2-pyridylpyrazine-κ(2)
n
(2),n
(3))bis(thiocyanato-κs)palladium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274878/ https://www.ncbi.nlm.nih.gov/pubmed/22346825 http://dx.doi.org/10.1107/S1600536812000980 |
work_keys_str_mv | AT hakwang 23di2pyridylpyrazinek2n2n3bisthiocyanatokspalladiumii |