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Di-μ-chlorido-bis{bis[4-(adamantan-1-ylcarbamoyl)pyridine-κN]chloridocopper(II)} hemihydrate
In the centrosymmetric dimeric title compound, [Cu(2)Cl(4)(C(16)H(20)N(2)O)(4)]·0.5H(2)O, the Cu(II) atom is in a distorted trigonal–bipyramidal environment defined by two bridging Cl atoms, one terminal Cl atom and two N atoms from two monodentate 4-(adamantan-1-ylcarbamoyl)pyridine ligands. The a...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274881/ https://www.ncbi.nlm.nih.gov/pubmed/22346828 http://dx.doi.org/10.1107/S1600536812000670 |
Sumario: | In the centrosymmetric dimeric title compound, [Cu(2)Cl(4)(C(16)H(20)N(2)O)(4)]·0.5H(2)O, the Cu(II) atom is in a distorted trigonal–bipyramidal environment defined by two bridging Cl atoms, one terminal Cl atom and two N atoms from two monodentate 4-(adamantan-1-ylcarbamoyl)pyridine ligands. The amine N atoms are involved in intramolecular N—H⋯O and intermolecular N—H⋯Cl hydrogen bonds. The latter hydrogen bonds link the complex molecules into a ribbon along [010]. The uncoordinated water molecule is 0.25-occupied. |
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