Di-μ-chlorido-bis­{bis­[4-(adamantan-1-ylcarbamo­yl)pyridine-κN]chlorido­copper(II)} hemihydrate

In the centrosymmetric dimeric title compound, [Cu(2)Cl(4)(C(16)H(20)N(2)O)(4)]·0.5H(2)O, the Cu(II) atom is in a distorted trigonal–bipyramidal environment defined by two bridging Cl atoms, one terminal Cl atom and two N atoms from two monodentate 4-(adamantan-1-ylcarbamo­yl)pyridine ligands. The a...

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Detalles Bibliográficos
Autor principal: Wang, Ying-Chun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274881/
https://www.ncbi.nlm.nih.gov/pubmed/22346828
http://dx.doi.org/10.1107/S1600536812000670
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author Wang, Ying-Chun
author_facet Wang, Ying-Chun
author_sort Wang, Ying-Chun
collection PubMed
description In the centrosymmetric dimeric title compound, [Cu(2)Cl(4)(C(16)H(20)N(2)O)(4)]·0.5H(2)O, the Cu(II) atom is in a distorted trigonal–bipyramidal environment defined by two bridging Cl atoms, one terminal Cl atom and two N atoms from two monodentate 4-(adamantan-1-ylcarbamo­yl)pyridine ligands. The amine N atoms are involved in intra­molecular N—H⋯O and inter­molecular N—H⋯Cl hydrogen bonds. The latter hydrogen bonds link the complex mol­ecules into a ribbon along [010]. The uncoordinated water mol­ecule is 0.25-occupied.
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spelling pubmed-32748812012-02-15 Di-μ-chlorido-bis­{bis­[4-(adamantan-1-ylcarbamo­yl)pyridine-κN]chlorido­copper(II)} hemihydrate Wang, Ying-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dimeric title compound, [Cu(2)Cl(4)(C(16)H(20)N(2)O)(4)]·0.5H(2)O, the Cu(II) atom is in a distorted trigonal–bipyramidal environment defined by two bridging Cl atoms, one terminal Cl atom and two N atoms from two monodentate 4-(adamantan-1-ylcarbamo­yl)pyridine ligands. The amine N atoms are involved in intra­molecular N—H⋯O and inter­molecular N—H⋯Cl hydrogen bonds. The latter hydrogen bonds link the complex mol­ecules into a ribbon along [010]. The uncoordinated water mol­ecule is 0.25-occupied. International Union of Crystallography 2012-01-14 /pmc/articles/PMC3274881/ /pubmed/22346828 http://dx.doi.org/10.1107/S1600536812000670 Text en © Ying-Chun Wang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Ying-Chun
Di-μ-chlorido-bis­{bis­[4-(adamantan-1-ylcarbamo­yl)pyridine-κN]chlorido­copper(II)} hemihydrate
title Di-μ-chlorido-bis­{bis­[4-(adamantan-1-ylcarbamo­yl)pyridine-κN]chlorido­copper(II)} hemihydrate
title_full Di-μ-chlorido-bis­{bis­[4-(adamantan-1-ylcarbamo­yl)pyridine-κN]chlorido­copper(II)} hemihydrate
title_fullStr Di-μ-chlorido-bis­{bis­[4-(adamantan-1-ylcarbamo­yl)pyridine-κN]chlorido­copper(II)} hemihydrate
title_full_unstemmed Di-μ-chlorido-bis­{bis­[4-(adamantan-1-ylcarbamo­yl)pyridine-κN]chlorido­copper(II)} hemihydrate
title_short Di-μ-chlorido-bis­{bis­[4-(adamantan-1-ylcarbamo­yl)pyridine-κN]chlorido­copper(II)} hemihydrate
title_sort di-μ-chlorido-bis­{bis­[4-(adamantan-1-ylcarbamo­yl)pyridine-κn]chlorido­copper(ii)} hemihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274881/
https://www.ncbi.nlm.nih.gov/pubmed/22346828
http://dx.doi.org/10.1107/S1600536812000670
work_keys_str_mv AT wangyingchun dimchloridobisbis4adamantan1ylcarbamoylpyridineknchloridocopperiihemihydrate

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