Cargando…

Bis(2-ethyl-1H-imidazol-3-ium) tetra­chloridomercurate(II)

The crystal structure of the title compound, (C(5)H(9)N(2))(2)[HgCl(4)], consists of discrete tetra­chloridomercurate dications and discrete 2-methyl­imidazolium cations. In the complex anion, the mercury cations are coordinated by four chloride anions with distances between 2.4568 (14) and 2.4936 (...

Descripción completa

Detalles Bibliográficos
Autor principal: Zhu, Run-Qiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274882/
https://www.ncbi.nlm.nih.gov/pubmed/22346829
http://dx.doi.org/10.1107/S1600536811055371
Descripción
Sumario:The crystal structure of the title compound, (C(5)H(9)N(2))(2)[HgCl(4)], consists of discrete tetra­chloridomercurate dications and discrete 2-methyl­imidazolium cations. In the complex anion, the mercury cations are coordinated by four chloride anions with distances between 2.4568 (14) and 2.4936 (15) Å in a tetra­hedral geometry. In the crystal, the cations and anions are connected by inter­molecular N—H⋯Cl inter­actions. One C atom of the cations is disordered and was refined using a split model (occupancy ratio 0.75:0.25).