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Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridomercurate(II)
The crystal structure of the title compound, (C(5)H(9)N(2))(2)[HgCl(4)], consists of discrete tetrachloridomercurate dications and discrete 2-methylimidazolium cations. In the complex anion, the mercury cations are coordinated by four chloride anions with distances between 2.4568 (14) and 2.4936 (...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2012
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274882/ https://www.ncbi.nlm.nih.gov/pubmed/22346829 http://dx.doi.org/10.1107/S1600536811055371 |
| _version_ | 1782223126903390208 |
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| author | Zhu, Run-Qiang |
| author_facet | Zhu, Run-Qiang |
| author_sort | Zhu, Run-Qiang |
| collection | PubMed |
| description | The crystal structure of the title compound, (C(5)H(9)N(2))(2)[HgCl(4)], consists of discrete tetrachloridomercurate dications and discrete 2-methylimidazolium cations. In the complex anion, the mercury cations are coordinated by four chloride anions with distances between 2.4568 (14) and 2.4936 (15) Å in a tetrahedral geometry. In the crystal, the cations and anions are connected by intermolecular N—H⋯Cl interactions. One C atom of the cations is disordered and was refined using a split model (occupancy ratio 0.75:0.25). |
| format | Online Article Text |
| id | pubmed-3274882 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32748822012-02-15 Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridomercurate(II) Zhu, Run-Qiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, (C(5)H(9)N(2))(2)[HgCl(4)], consists of discrete tetrachloridomercurate dications and discrete 2-methylimidazolium cations. In the complex anion, the mercury cations are coordinated by four chloride anions with distances between 2.4568 (14) and 2.4936 (15) Å in a tetrahedral geometry. In the crystal, the cations and anions are connected by intermolecular N—H⋯Cl interactions. One C atom of the cations is disordered and was refined using a split model (occupancy ratio 0.75:0.25). International Union of Crystallography 2012-01-14 /pmc/articles/PMC3274882/ /pubmed/22346829 http://dx.doi.org/10.1107/S1600536811055371 Text en © Run-Qiang Zhu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhu, Run-Qiang Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridomercurate(II) |
| title | Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridomercurate(II) |
| title_full | Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridomercurate(II) |
| title_fullStr | Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridomercurate(II) |
| title_full_unstemmed | Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridomercurate(II) |
| title_short | Bis(2-ethyl-1H-imidazol-3-ium) tetrachloridomercurate(II) |
| title_sort | bis(2-ethyl-1h-imidazol-3-ium) tetrachloridomercurate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274882/ https://www.ncbi.nlm.nih.gov/pubmed/22346829 http://dx.doi.org/10.1107/S1600536811055371 |
| work_keys_str_mv | AT zhurunqiang bis2ethyl1himidazol3iumtetrachloridomercurateii |