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catena-Poly[copper(II)-bis(μ-2-formyl-6-methoxyphenolato-κ(4) O (2),O (1):O (1),O (6))-[(methanol-κO)sodium]-μ-perchlorato-κ(2) O:O′]
In the title heterodinuclear complex, [CuNa(C(8)H(7)O(3))(2)(ClO(4))(CH(3)OH)](n), the Cu(II) ion is five-coordinated by four O atoms from two 2-formyl-6-methoxyphenolate anions and one O atom from a perchlorate anion in a distorted square-pyramidal geometry. The Na(+) ion is six-coordinated by fo...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274885/ https://www.ncbi.nlm.nih.gov/pubmed/22346832 http://dx.doi.org/10.1107/S1600536812000876 |
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author | Gao, Ting Gao, Po Li, Hong-Feng Zhang, Ju-Wen Xu, Li-Li |
author_facet | Gao, Ting Gao, Po Li, Hong-Feng Zhang, Ju-Wen Xu, Li-Li |
author_sort | Gao, Ting |
collection | PubMed |
description | In the title heterodinuclear complex, [CuNa(C(8)H(7)O(3))(2)(ClO(4))(CH(3)OH)](n), the Cu(II) ion is five-coordinated by four O atoms from two 2-formyl-6-methoxyphenolate anions and one O atom from a perchlorate anion in a distorted square-pyramidal geometry. The Na(+) ion is six-coordinated by four O atoms from two 2-formyl-6-methoxyphenolate ligands, one O atom of a methanol molecule and one O atom of a perchlorate anion. The perchlorate anions link the Na(+) and Cu(II) ions, forming a chain along [010]. O—H⋯O hydrogen bonds connect the chains. π–π interactions are present between the benzene rings [centroid–centroid distances = 3.566 (2) and 3.702 (2) Å]. The O atoms of the perchlorate anion are disordered over two sets of sites, with an occupancy ratio of 0.481 (8):0.519 (8). |
format | Online Article Text |
id | pubmed-3274885 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32748852012-02-15 catena-Poly[copper(II)-bis(μ-2-formyl-6-methoxyphenolato-κ(4) O (2),O (1):O (1),O (6))-[(methanol-κO)sodium]-μ-perchlorato-κ(2) O:O′] Gao, Ting Gao, Po Li, Hong-Feng Zhang, Ju-Wen Xu, Li-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title heterodinuclear complex, [CuNa(C(8)H(7)O(3))(2)(ClO(4))(CH(3)OH)](n), the Cu(II) ion is five-coordinated by four O atoms from two 2-formyl-6-methoxyphenolate anions and one O atom from a perchlorate anion in a distorted square-pyramidal geometry. The Na(+) ion is six-coordinated by four O atoms from two 2-formyl-6-methoxyphenolate ligands, one O atom of a methanol molecule and one O atom of a perchlorate anion. The perchlorate anions link the Na(+) and Cu(II) ions, forming a chain along [010]. O—H⋯O hydrogen bonds connect the chains. π–π interactions are present between the benzene rings [centroid–centroid distances = 3.566 (2) and 3.702 (2) Å]. The O atoms of the perchlorate anion are disordered over two sets of sites, with an occupancy ratio of 0.481 (8):0.519 (8). International Union of Crystallography 2012-01-14 /pmc/articles/PMC3274885/ /pubmed/22346832 http://dx.doi.org/10.1107/S1600536812000876 Text en © Gao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gao, Ting Gao, Po Li, Hong-Feng Zhang, Ju-Wen Xu, Li-Li catena-Poly[copper(II)-bis(μ-2-formyl-6-methoxyphenolato-κ(4) O (2),O (1):O (1),O (6))-[(methanol-κO)sodium]-μ-perchlorato-κ(2) O:O′] |
title |
catena-Poly[copper(II)-bis(μ-2-formyl-6-methoxyphenolato-κ(4)
O
(2),O
(1):O
(1),O
(6))-[(methanol-κO)sodium]-μ-perchlorato-κ(2)
O:O′] |
title_full |
catena-Poly[copper(II)-bis(μ-2-formyl-6-methoxyphenolato-κ(4)
O
(2),O
(1):O
(1),O
(6))-[(methanol-κO)sodium]-μ-perchlorato-κ(2)
O:O′] |
title_fullStr |
catena-Poly[copper(II)-bis(μ-2-formyl-6-methoxyphenolato-κ(4)
O
(2),O
(1):O
(1),O
(6))-[(methanol-κO)sodium]-μ-perchlorato-κ(2)
O:O′] |
title_full_unstemmed |
catena-Poly[copper(II)-bis(μ-2-formyl-6-methoxyphenolato-κ(4)
O
(2),O
(1):O
(1),O
(6))-[(methanol-κO)sodium]-μ-perchlorato-κ(2)
O:O′] |
title_short |
catena-Poly[copper(II)-bis(μ-2-formyl-6-methoxyphenolato-κ(4)
O
(2),O
(1):O
(1),O
(6))-[(methanol-κO)sodium]-μ-perchlorato-κ(2)
O:O′] |
title_sort | catena-poly[copper(ii)-bis(μ-2-formyl-6-methoxyphenolato-κ(4)
o
(2),o
(1):o
(1),o
(6))-[(methanol-κo)sodium]-μ-perchlorato-κ(2)
o:o′] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274885/ https://www.ncbi.nlm.nih.gov/pubmed/22346832 http://dx.doi.org/10.1107/S1600536812000876 |
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