Bis{2,2′-[(2-amino­eth­yl)aza­nedi­yl]diethanaminium} di-μ-sulfido-bis­(disulfido­germanate)

In the title compound, (C(6)H(20)N(4))(2)[Ge(2)S(6)], the dimeric [Ge(2)S(6)](4−) anion is formed by two edge-sharing GeS(4) tetra­hedral units. The average terminal and bridging Ge—S bond lengths are 2.158 (14) and 2.276 (6) Å, respectively. The anions and the diprotonated ammonium cations are orga...

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Autores principales: Xu, Chao, Zhang, Jing-Jing, Duan, Taike, Chen, Qun, Zhang, Qian-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274887/
https://www.ncbi.nlm.nih.gov/pubmed/22346834
http://dx.doi.org/10.1107/S160053681200092X
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author Xu, Chao
Zhang, Jing-Jing
Duan, Taike
Chen, Qun
Zhang, Qian-Feng
author_facet Xu, Chao
Zhang, Jing-Jing
Duan, Taike
Chen, Qun
Zhang, Qian-Feng
author_sort Xu, Chao
collection PubMed
description In the title compound, (C(6)H(20)N(4))(2)[Ge(2)S(6)], the dimeric [Ge(2)S(6)](4−) anion is formed by two edge-sharing GeS(4) tetra­hedral units. The average terminal and bridging Ge—S bond lengths are 2.158 (14) and 2.276 (6) Å, respectively. The anions and the diprotonated ammonium cations are organized into a three-dimensional network by N—H⋯S and N—H⋯N hydrogen bonds.
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spelling pubmed-32748872012-02-15 Bis{2,2′-[(2-amino­eth­yl)aza­nedi­yl]diethanaminium} di-μ-sulfido-bis­(disulfido­germanate) Xu, Chao Zhang, Jing-Jing Duan, Taike Chen, Qun Zhang, Qian-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(6)H(20)N(4))(2)[Ge(2)S(6)], the dimeric [Ge(2)S(6)](4−) anion is formed by two edge-sharing GeS(4) tetra­hedral units. The average terminal and bridging Ge—S bond lengths are 2.158 (14) and 2.276 (6) Å, respectively. The anions and the diprotonated ammonium cations are organized into a three-dimensional network by N—H⋯S and N—H⋯N hydrogen bonds. International Union of Crystallography 2012-01-14 /pmc/articles/PMC3274887/ /pubmed/22346834 http://dx.doi.org/10.1107/S160053681200092X Text en © Xu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Chao
Zhang, Jing-Jing
Duan, Taike
Chen, Qun
Zhang, Qian-Feng
Bis{2,2′-[(2-amino­eth­yl)aza­nedi­yl]diethanaminium} di-μ-sulfido-bis­(disulfido­germanate)
title Bis{2,2′-[(2-amino­eth­yl)aza­nedi­yl]diethanaminium} di-μ-sulfido-bis­(disulfido­germanate)
title_full Bis{2,2′-[(2-amino­eth­yl)aza­nedi­yl]diethanaminium} di-μ-sulfido-bis­(disulfido­germanate)
title_fullStr Bis{2,2′-[(2-amino­eth­yl)aza­nedi­yl]diethanaminium} di-μ-sulfido-bis­(disulfido­germanate)
title_full_unstemmed Bis{2,2′-[(2-amino­eth­yl)aza­nedi­yl]diethanaminium} di-μ-sulfido-bis­(disulfido­germanate)
title_short Bis{2,2′-[(2-amino­eth­yl)aza­nedi­yl]diethanaminium} di-μ-sulfido-bis­(disulfido­germanate)
title_sort bis{2,2′-[(2-amino­eth­yl)aza­nedi­yl]diethanaminium} di-μ-sulfido-bis­(disulfido­germanate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274887/
https://www.ncbi.nlm.nih.gov/pubmed/22346834
http://dx.doi.org/10.1107/S160053681200092X
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