μ-1,4-Bis(pyridin-4-ylmeth­yl)piperazine-κ(2) N:N′-bis­[aqua­bis­(3-bromo-5-carb­oxy­benzoato-κO (1))copper(II)]

In the title compound, [Cu(2)(C(8)H(4)BrO(4))(4)(C(16)H(20)N(4))(H(2)O)(2)], slightly distorted square-planar-coordinated Cu(II) ions are bound by one aqua ligand and two monodentate 3-bromo-5-carb­oxy­benzoate anions, and linked into a centrosymmetric dinuclear mol­ecule by a bridging 1,4-bis­(pyri...

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Detalles Bibliográficos
Autores principales: Meyer, Jodi L., LaDuca, Robert L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274888/
https://www.ncbi.nlm.nih.gov/pubmed/22346835
http://dx.doi.org/10.1107/S1600536812000979
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author Meyer, Jodi L.
LaDuca, Robert L.
author_facet Meyer, Jodi L.
LaDuca, Robert L.
author_sort Meyer, Jodi L.
collection PubMed
description In the title compound, [Cu(2)(C(8)H(4)BrO(4))(4)(C(16)H(20)N(4))(H(2)O)(2)], slightly distorted square-planar-coordinated Cu(II) ions are bound by one aqua ligand and two monodentate 3-bromo-5-carb­oxy­benzoate anions, and linked into a centrosymmetric dinuclear mol­ecule by a bridging 1,4-bis­(pyridin-4-ylmeth­yl)piperazine (4-bpmp) ligand. In the crystal, mol­ecules are connected into a supra­molecular two-dimensional network parallel to (131) via O—H⋯O hydrogen bonds involving the aqua ligands and 3-bromo-5-carb­oxy­benzoate carboxyl­ate groups.
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spelling pubmed-32748882012-02-15 μ-1,4-Bis(pyridin-4-ylmeth­yl)piperazine-κ(2) N:N′-bis­[aqua­bis­(3-bromo-5-carb­oxy­benzoato-κO (1))copper(II)] Meyer, Jodi L. LaDuca, Robert L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(2)(C(8)H(4)BrO(4))(4)(C(16)H(20)N(4))(H(2)O)(2)], slightly distorted square-planar-coordinated Cu(II) ions are bound by one aqua ligand and two monodentate 3-bromo-5-carb­oxy­benzoate anions, and linked into a centrosymmetric dinuclear mol­ecule by a bridging 1,4-bis­(pyridin-4-ylmeth­yl)piperazine (4-bpmp) ligand. In the crystal, mol­ecules are connected into a supra­molecular two-dimensional network parallel to (131) via O—H⋯O hydrogen bonds involving the aqua ligands and 3-bromo-5-carb­oxy­benzoate carboxyl­ate groups. International Union of Crystallography 2012-01-14 /pmc/articles/PMC3274888/ /pubmed/22346835 http://dx.doi.org/10.1107/S1600536812000979 Text en © Meyer and LaDuca 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meyer, Jodi L.
LaDuca, Robert L.
μ-1,4-Bis(pyridin-4-ylmeth­yl)piperazine-κ(2) N:N′-bis­[aqua­bis­(3-bromo-5-carb­oxy­benzoato-κO (1))copper(II)]
title μ-1,4-Bis(pyridin-4-ylmeth­yl)piperazine-κ(2) N:N′-bis­[aqua­bis­(3-bromo-5-carb­oxy­benzoato-κO (1))copper(II)]
title_full μ-1,4-Bis(pyridin-4-ylmeth­yl)piperazine-κ(2) N:N′-bis­[aqua­bis­(3-bromo-5-carb­oxy­benzoato-κO (1))copper(II)]
title_fullStr μ-1,4-Bis(pyridin-4-ylmeth­yl)piperazine-κ(2) N:N′-bis­[aqua­bis­(3-bromo-5-carb­oxy­benzoato-κO (1))copper(II)]
title_full_unstemmed μ-1,4-Bis(pyridin-4-ylmeth­yl)piperazine-κ(2) N:N′-bis­[aqua­bis­(3-bromo-5-carb­oxy­benzoato-κO (1))copper(II)]
title_short μ-1,4-Bis(pyridin-4-ylmeth­yl)piperazine-κ(2) N:N′-bis­[aqua­bis­(3-bromo-5-carb­oxy­benzoato-κO (1))copper(II)]
title_sort μ-1,4-bis(pyridin-4-ylmeth­yl)piperazine-κ(2) n:n′-bis­[aqua­bis­(3-bromo-5-carb­oxy­benzoato-κo (1))copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274888/
https://www.ncbi.nlm.nih.gov/pubmed/22346835
http://dx.doi.org/10.1107/S1600536812000979
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