Butyl­bis­(dimethyl­glyoximato-κ(2) N,N′)(pyridine-κN)cobalt(III)

In the title compound, [Co(C(4)H(9))(C(4)H(7)N(2)O(2))(2)(C(5)H(5)N)], which was prepared as a model complex of vitamin B(12), the Co(III) atom is coordinated by a butyl group, a pyridine and two N,N′-bidentate dimethyl­glyoximate ligands in a distorted octa­hedral geometry. The bis-chelating dimeth...

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Detalles Bibliográficos
Autores principales: Kumar, Sarvendra, Thapa, Suresh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274889/
https://www.ncbi.nlm.nih.gov/pubmed/22346836
http://dx.doi.org/10.1107/S1600536812000967
Descripción
Sumario:In the title compound, [Co(C(4)H(9))(C(4)H(7)N(2)O(2))(2)(C(5)H(5)N)], which was prepared as a model complex of vitamin B(12), the Co(III) atom is coordinated by a butyl group, a pyridine and two N,N′-bidentate dimethyl­glyoximate ligands in a distorted octa­hedral geometry. The bis-chelating dimethyl­glyoximate ligands, which occupy equatorial sites, are linked by strong intra­molecular O—H⋯O hydrogen bonds.

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