Butyl­bis­(dimethyl­glyoximato-κ(2) N,N′)(pyridine-κN)cobalt(III)

In the title compound, [Co(C(4)H(9))(C(4)H(7)N(2)O(2))(2)(C(5)H(5)N)], which was prepared as a model complex of vitamin B(12), the Co(III) atom is coordinated by a butyl group, a pyridine and two N,N′-bidentate dimethyl­glyoximate ligands in a distorted octa­hedral geometry. The bis-chelating dimeth...

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Detalles Bibliográficos
Autores principales: Kumar, Sarvendra, Thapa, Suresh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274889/
https://www.ncbi.nlm.nih.gov/pubmed/22346836
http://dx.doi.org/10.1107/S1600536812000967
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author Kumar, Sarvendra
Thapa, Suresh
author_facet Kumar, Sarvendra
Thapa, Suresh
author_sort Kumar, Sarvendra
collection PubMed
description In the title compound, [Co(C(4)H(9))(C(4)H(7)N(2)O(2))(2)(C(5)H(5)N)], which was prepared as a model complex of vitamin B(12), the Co(III) atom is coordinated by a butyl group, a pyridine and two N,N′-bidentate dimethyl­glyoximate ligands in a distorted octa­hedral geometry. The bis-chelating dimethyl­glyoximate ligands, which occupy equatorial sites, are linked by strong intra­molecular O—H⋯O hydrogen bonds.
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spelling pubmed-32748892012-02-15 Butyl­bis­(dimethyl­glyoximato-κ(2) N,N′)(pyridine-κN)cobalt(III) Kumar, Sarvendra Thapa, Suresh Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(4)H(9))(C(4)H(7)N(2)O(2))(2)(C(5)H(5)N)], which was prepared as a model complex of vitamin B(12), the Co(III) atom is coordinated by a butyl group, a pyridine and two N,N′-bidentate dimethyl­glyoximate ligands in a distorted octa­hedral geometry. The bis-chelating dimethyl­glyoximate ligands, which occupy equatorial sites, are linked by strong intra­molecular O—H⋯O hydrogen bonds. International Union of Crystallography 2012-01-14 /pmc/articles/PMC3274889/ /pubmed/22346836 http://dx.doi.org/10.1107/S1600536812000967 Text en © Kumar and Thapa 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kumar, Sarvendra
Thapa, Suresh
Butyl­bis­(dimethyl­glyoximato-κ(2) N,N′)(pyridine-κN)cobalt(III)
title Butyl­bis­(dimethyl­glyoximato-κ(2) N,N′)(pyridine-κN)cobalt(III)
title_full Butyl­bis­(dimethyl­glyoximato-κ(2) N,N′)(pyridine-κN)cobalt(III)
title_fullStr Butyl­bis­(dimethyl­glyoximato-κ(2) N,N′)(pyridine-κN)cobalt(III)
title_full_unstemmed Butyl­bis­(dimethyl­glyoximato-κ(2) N,N′)(pyridine-κN)cobalt(III)
title_short Butyl­bis­(dimethyl­glyoximato-κ(2) N,N′)(pyridine-κN)cobalt(III)
title_sort butyl­bis­(dimethyl­glyoximato-κ(2) n,n′)(pyridine-κn)cobalt(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274889/
https://www.ncbi.nlm.nih.gov/pubmed/22346836
http://dx.doi.org/10.1107/S1600536812000967
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