4-[(4′-Chloro­methyl-[1,1′-biphen­yl]-4-yl)meth­yl]bis­(dimethyl­glyoximato-κ(2) N,N′)(pyridine-κN)cobalt(III)

The title compound, [Co(C(14)H(14)Cl)(C(4)H(6)N(2)O(2))(2)(C(5)H(5)N)], is a model compound for the more complex cobalamines like vitamins B(12). The Co(III) atom is coordinated by a (4′-chloro­methyl-[1,1′-biphen­yl]-4-yl)methyl group, an N-bonded pyridine and two N,N′-bidentate dimethyl­glyoximate...

Descripción completa

Detalles Bibliográficos
Autores principales: Kumar, Sarvendra, Thapa, Suresh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274891/
https://www.ncbi.nlm.nih.gov/pubmed/22346838
http://dx.doi.org/10.1107/S1600536812001092
_version_ 1782223129015222272
author Kumar, Sarvendra
Thapa, Suresh
author_facet Kumar, Sarvendra
Thapa, Suresh
author_sort Kumar, Sarvendra
collection PubMed
description The title compound, [Co(C(14)H(14)Cl)(C(4)H(6)N(2)O(2))(2)(C(5)H(5)N)], is a model compound for the more complex cobalamines like vitamins B(12). The Co(III) atom is coordinated by a (4′-chloro­methyl-[1,1′-biphen­yl]-4-yl)methyl group, an N-bonded pyridine and two N,N′-bidentate dimethyl­glyoximate ligands in a distorted octa­hedral geometry. The glyoximate ligands exhibit intra­molecular O—H⋯O hydrogen bonds, which is very common in cobaloxime derivatives.
format Online
Article
Text
id pubmed-3274891
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32748912012-02-15 4-[(4′-Chloro­methyl-[1,1′-biphen­yl]-4-yl)meth­yl]bis­(dimethyl­glyoximato-κ(2) N,N′)(pyridine-κN)cobalt(III) Kumar, Sarvendra Thapa, Suresh Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(14)H(14)Cl)(C(4)H(6)N(2)O(2))(2)(C(5)H(5)N)], is a model compound for the more complex cobalamines like vitamins B(12). The Co(III) atom is coordinated by a (4′-chloro­methyl-[1,1′-biphen­yl]-4-yl)methyl group, an N-bonded pyridine and two N,N′-bidentate dimethyl­glyoximate ligands in a distorted octa­hedral geometry. The glyoximate ligands exhibit intra­molecular O—H⋯O hydrogen bonds, which is very common in cobaloxime derivatives. International Union of Crystallography 2012-01-14 /pmc/articles/PMC3274891/ /pubmed/22346838 http://dx.doi.org/10.1107/S1600536812001092 Text en © Kumar and Thapa 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kumar, Sarvendra
Thapa, Suresh
4-[(4′-Chloro­methyl-[1,1′-biphen­yl]-4-yl)meth­yl]bis­(dimethyl­glyoximato-κ(2) N,N′)(pyridine-κN)cobalt(III)
title 4-[(4′-Chloro­methyl-[1,1′-biphen­yl]-4-yl)meth­yl]bis­(dimethyl­glyoximato-κ(2) N,N′)(pyridine-κN)cobalt(III)
title_full 4-[(4′-Chloro­methyl-[1,1′-biphen­yl]-4-yl)meth­yl]bis­(dimethyl­glyoximato-κ(2) N,N′)(pyridine-κN)cobalt(III)
title_fullStr 4-[(4′-Chloro­methyl-[1,1′-biphen­yl]-4-yl)meth­yl]bis­(dimethyl­glyoximato-κ(2) N,N′)(pyridine-κN)cobalt(III)
title_full_unstemmed 4-[(4′-Chloro­methyl-[1,1′-biphen­yl]-4-yl)meth­yl]bis­(dimethyl­glyoximato-κ(2) N,N′)(pyridine-κN)cobalt(III)
title_short 4-[(4′-Chloro­methyl-[1,1′-biphen­yl]-4-yl)meth­yl]bis­(dimethyl­glyoximato-κ(2) N,N′)(pyridine-κN)cobalt(III)
title_sort 4-[(4′-chloro­methyl-[1,1′-biphen­yl]-4-yl)meth­yl]bis­(dimethyl­glyoximato-κ(2) n,n′)(pyridine-κn)cobalt(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274891/
https://www.ncbi.nlm.nih.gov/pubmed/22346838
http://dx.doi.org/10.1107/S1600536812001092
work_keys_str_mv AT kumarsarvendra 44chloromethyl11biphenyl4ylmethylbisdimethylglyoximatok2nnpyridinekncobaltiii
AT thapasuresh 44chloromethyl11biphenyl4ylmethylbisdimethylglyoximatok2nnpyridinekncobaltiii

Ejemplares similares