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Poly[(μ(2)-quinoline-3-carboxyl­ato-κ(2) N:O)(μ(2)-quinoline-3-carboxyl­ato-κ(3) N:O,O′)cadmium]

In the title compound, [Cd(C(10)H(6)NO(2))(2)](n), the Cd(II) atom is coordinated by three O atoms and two N atoms from four quinoline-3-carboxyl­ate (L (−)) ligands, leading to a distorted trigonal–bipyramidal geometry. The L (−) ligands link the Cd(II) atoms into a plane parallel to (100), with on...

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Detalles Bibliográficos
Autores principales: Wang, Xing, Yan, Yong-Sheng, Sun, He-Yi, Wang, Shen-Tang, Liu, Chun-Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274893/
https://www.ncbi.nlm.nih.gov/pubmed/22346840
http://dx.doi.org/10.1107/S1600536812001031
Descripción
Sumario:In the title compound, [Cd(C(10)H(6)NO(2))(2)](n), the Cd(II) atom is coordinated by three O atoms and two N atoms from four quinoline-3-carboxyl­ate (L (−)) ligands, leading to a distorted trigonal–bipyramidal geometry. The L (−) ligands link the Cd(II) atoms into a plane parallel to (100), with one ligand being tridentate, coordinating via the N atom and chelating a second Cd atom, and the other being bidentate, bridging two Cd atoms via the N and one O atom.. This two-dimensional network extends into a double-layer network by π–π inter­actions, with centroid–centroid distances of 3.680 (2) and 3.752 (2) Å. Another type of π–π inter­action between pyridine rings [centroid–centroid distance = 3.527 (2) Å] leads to a three-dimensional supra­molecular architecture.