Cargando…
Poly[(μ(2)-quinoline-3-carboxylato-κ(2) N:O)(μ(2)-quinoline-3-carboxylato-κ(3) N:O,O′)cadmium]
In the title compound, [Cd(C(10)H(6)NO(2))(2)](n), the Cd(II) atom is coordinated by three O atoms and two N atoms from four quinoline-3-carboxylate (L (−)) ligands, leading to a distorted trigonal–bipyramidal geometry. The L (−) ligands link the Cd(II) atoms into a plane parallel to (100), with on...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274893/ https://www.ncbi.nlm.nih.gov/pubmed/22346840 http://dx.doi.org/10.1107/S1600536812001031 |
_version_ | 1782223129496518656 |
---|---|
author | Wang, Xing Yan, Yong-Sheng Sun, He-Yi Wang, Shen-Tang Liu, Chun-Bo |
author_facet | Wang, Xing Yan, Yong-Sheng Sun, He-Yi Wang, Shen-Tang Liu, Chun-Bo |
author_sort | Wang, Xing |
collection | PubMed |
description | In the title compound, [Cd(C(10)H(6)NO(2))(2)](n), the Cd(II) atom is coordinated by three O atoms and two N atoms from four quinoline-3-carboxylate (L (−)) ligands, leading to a distorted trigonal–bipyramidal geometry. The L (−) ligands link the Cd(II) atoms into a plane parallel to (100), with one ligand being tridentate, coordinating via the N atom and chelating a second Cd atom, and the other being bidentate, bridging two Cd atoms via the N and one O atom.. This two-dimensional network extends into a double-layer network by π–π interactions, with centroid–centroid distances of 3.680 (2) and 3.752 (2) Å. Another type of π–π interaction between pyridine rings [centroid–centroid distance = 3.527 (2) Å] leads to a three-dimensional supramolecular architecture. |
format | Online Article Text |
id | pubmed-3274893 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32748932012-02-15 Poly[(μ(2)-quinoline-3-carboxylato-κ(2) N:O)(μ(2)-quinoline-3-carboxylato-κ(3) N:O,O′)cadmium] Wang, Xing Yan, Yong-Sheng Sun, He-Yi Wang, Shen-Tang Liu, Chun-Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(10)H(6)NO(2))(2)](n), the Cd(II) atom is coordinated by three O atoms and two N atoms from four quinoline-3-carboxylate (L (−)) ligands, leading to a distorted trigonal–bipyramidal geometry. The L (−) ligands link the Cd(II) atoms into a plane parallel to (100), with one ligand being tridentate, coordinating via the N atom and chelating a second Cd atom, and the other being bidentate, bridging two Cd atoms via the N and one O atom.. This two-dimensional network extends into a double-layer network by π–π interactions, with centroid–centroid distances of 3.680 (2) and 3.752 (2) Å. Another type of π–π interaction between pyridine rings [centroid–centroid distance = 3.527 (2) Å] leads to a three-dimensional supramolecular architecture. International Union of Crystallography 2012-01-18 /pmc/articles/PMC3274893/ /pubmed/22346840 http://dx.doi.org/10.1107/S1600536812001031 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Xing Yan, Yong-Sheng Sun, He-Yi Wang, Shen-Tang Liu, Chun-Bo Poly[(μ(2)-quinoline-3-carboxylato-κ(2) N:O)(μ(2)-quinoline-3-carboxylato-κ(3) N:O,O′)cadmium] |
title | Poly[(μ(2)-quinoline-3-carboxylato-κ(2)
N:O)(μ(2)-quinoline-3-carboxylato-κ(3)
N:O,O′)cadmium] |
title_full | Poly[(μ(2)-quinoline-3-carboxylato-κ(2)
N:O)(μ(2)-quinoline-3-carboxylato-κ(3)
N:O,O′)cadmium] |
title_fullStr | Poly[(μ(2)-quinoline-3-carboxylato-κ(2)
N:O)(μ(2)-quinoline-3-carboxylato-κ(3)
N:O,O′)cadmium] |
title_full_unstemmed | Poly[(μ(2)-quinoline-3-carboxylato-κ(2)
N:O)(μ(2)-quinoline-3-carboxylato-κ(3)
N:O,O′)cadmium] |
title_short | Poly[(μ(2)-quinoline-3-carboxylato-κ(2)
N:O)(μ(2)-quinoline-3-carboxylato-κ(3)
N:O,O′)cadmium] |
title_sort | poly[(μ(2)-quinoline-3-carboxylato-κ(2)
n:o)(μ(2)-quinoline-3-carboxylato-κ(3)
n:o,o′)cadmium] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274893/ https://www.ncbi.nlm.nih.gov/pubmed/22346840 http://dx.doi.org/10.1107/S1600536812001031 |
work_keys_str_mv | AT wangxing polym2quinoline3carboxylatok2nom2quinoline3carboxylatok3noocadmium AT yanyongsheng polym2quinoline3carboxylatok2nom2quinoline3carboxylatok3noocadmium AT sunheyi polym2quinoline3carboxylatok2nom2quinoline3carboxylatok3noocadmium AT wangshentang polym2quinoline3carboxylatok2nom2quinoline3carboxylatok3noocadmium AT liuchunbo polym2quinoline3carboxylatok2nom2quinoline3carboxylatok3noocadmium |