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Poly[(μ(2)-quinoline-3-carboxyl­ato-κ(2) N:O)(μ(2)-quinoline-3-carboxyl­ato-κ(3) N:O,O′)cadmium]

In the title compound, [Cd(C(10)H(6)NO(2))(2)](n), the Cd(II) atom is coordinated by three O atoms and two N atoms from four quinoline-3-carboxyl­ate (L (−)) ligands, leading to a distorted trigonal–bipyramidal geometry. The L (−) ligands link the Cd(II) atoms into a plane parallel to (100), with on...

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Autores principales: Wang, Xing, Yan, Yong-Sheng, Sun, He-Yi, Wang, Shen-Tang, Liu, Chun-Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274893/
https://www.ncbi.nlm.nih.gov/pubmed/22346840
http://dx.doi.org/10.1107/S1600536812001031
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author Wang, Xing
Yan, Yong-Sheng
Sun, He-Yi
Wang, Shen-Tang
Liu, Chun-Bo
author_facet Wang, Xing
Yan, Yong-Sheng
Sun, He-Yi
Wang, Shen-Tang
Liu, Chun-Bo
author_sort Wang, Xing
collection PubMed
description In the title compound, [Cd(C(10)H(6)NO(2))(2)](n), the Cd(II) atom is coordinated by three O atoms and two N atoms from four quinoline-3-carboxyl­ate (L (−)) ligands, leading to a distorted trigonal–bipyramidal geometry. The L (−) ligands link the Cd(II) atoms into a plane parallel to (100), with one ligand being tridentate, coordinating via the N atom and chelating a second Cd atom, and the other being bidentate, bridging two Cd atoms via the N and one O atom.. This two-dimensional network extends into a double-layer network by π–π inter­actions, with centroid–centroid distances of 3.680 (2) and 3.752 (2) Å. Another type of π–π inter­action between pyridine rings [centroid–centroid distance = 3.527 (2) Å] leads to a three-dimensional supra­molecular architecture.
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spelling pubmed-32748932012-02-15 Poly[(μ(2)-quinoline-3-carboxyl­ato-κ(2) N:O)(μ(2)-quinoline-3-carboxyl­ato-κ(3) N:O,O′)cadmium] Wang, Xing Yan, Yong-Sheng Sun, He-Yi Wang, Shen-Tang Liu, Chun-Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(10)H(6)NO(2))(2)](n), the Cd(II) atom is coordinated by three O atoms and two N atoms from four quinoline-3-carboxyl­ate (L (−)) ligands, leading to a distorted trigonal–bipyramidal geometry. The L (−) ligands link the Cd(II) atoms into a plane parallel to (100), with one ligand being tridentate, coordinating via the N atom and chelating a second Cd atom, and the other being bidentate, bridging two Cd atoms via the N and one O atom.. This two-dimensional network extends into a double-layer network by π–π inter­actions, with centroid–centroid distances of 3.680 (2) and 3.752 (2) Å. Another type of π–π inter­action between pyridine rings [centroid–centroid distance = 3.527 (2) Å] leads to a three-dimensional supra­molecular architecture. International Union of Crystallography 2012-01-18 /pmc/articles/PMC3274893/ /pubmed/22346840 http://dx.doi.org/10.1107/S1600536812001031 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Xing
Yan, Yong-Sheng
Sun, He-Yi
Wang, Shen-Tang
Liu, Chun-Bo
Poly[(μ(2)-quinoline-3-carboxyl­ato-κ(2) N:O)(μ(2)-quinoline-3-carboxyl­ato-κ(3) N:O,O′)cadmium]
title Poly[(μ(2)-quinoline-3-carboxyl­ato-κ(2) N:O)(μ(2)-quinoline-3-carboxyl­ato-κ(3) N:O,O′)cadmium]
title_full Poly[(μ(2)-quinoline-3-carboxyl­ato-κ(2) N:O)(μ(2)-quinoline-3-carboxyl­ato-κ(3) N:O,O′)cadmium]
title_fullStr Poly[(μ(2)-quinoline-3-carboxyl­ato-κ(2) N:O)(μ(2)-quinoline-3-carboxyl­ato-κ(3) N:O,O′)cadmium]
title_full_unstemmed Poly[(μ(2)-quinoline-3-carboxyl­ato-κ(2) N:O)(μ(2)-quinoline-3-carboxyl­ato-κ(3) N:O,O′)cadmium]
title_short Poly[(μ(2)-quinoline-3-carboxyl­ato-κ(2) N:O)(μ(2)-quinoline-3-carboxyl­ato-κ(3) N:O,O′)cadmium]
title_sort poly[(μ(2)-quinoline-3-carboxyl­ato-κ(2) n:o)(μ(2)-quinoline-3-carboxyl­ato-κ(3) n:o,o′)cadmium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274893/
https://www.ncbi.nlm.nih.gov/pubmed/22346840
http://dx.doi.org/10.1107/S1600536812001031
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