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Bis(4-cyano-1-methylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato-κ(2) S,S′)cuprate(II)
The title ion-pair compound, (C(7)H(7)N(2))(2)[Cu(C(4)N(2)S(2))(2)], was obtained by the direct reaction of CuCl(2)·2H(2)O, disodium maleonitriledithiolate (Na(2)mnt) and 4-cyano-1-methylpyridinium iodide. The anion and one pyridinium cation lie entirely on a mirror plane, whereas for the other c...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274894/ https://www.ncbi.nlm.nih.gov/pubmed/22346841 http://dx.doi.org/10.1107/S1600536812001377 |
Sumario: | The title ion-pair compound, (C(7)H(7)N(2))(2)[Cu(C(4)N(2)S(2))(2)], was obtained by the direct reaction of CuCl(2)·2H(2)O, disodium maleonitriledithiolate (Na(2)mnt) and 4-cyano-1-methylpyridinium iodide. The anion and one pyridinium cation lie entirely on a mirror plane, whereas for the other cation, a crystallographic mirror plane runs through the N and para-C atoms of the pyridine ring, the methyl C atom, and the cyano group. In the crystal, ions are linked into a three-dimensional network by C—H⋯N hydrogen bonds. |
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