Bis(4-cyano-1-methyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)cuprate(II)

The title ion-pair compound, (C(7)H(7)N(2))(2)[Cu(C(4)N(2)S(2))(2)], was obtained by the direct reaction of CuCl(2)·2H(2)O, disodium maleonitrile­dithiol­ate (Na(2)mnt) and 4-cyano-1-methyl­pyridinium iodide. The anion and one pyridinium cation lie entirely on a mirror plane, whereas for the other c...

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Detalles Bibliográficos
Autores principales: Wang, Na, Wang, Jin-Guo, Min, An-Jie, Fu, Yao-Wen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274894/
https://www.ncbi.nlm.nih.gov/pubmed/22346841
http://dx.doi.org/10.1107/S1600536812001377
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author Wang, Na
Wang, Jin-Guo
Min, An-Jie
Fu, Yao-Wen
author_facet Wang, Na
Wang, Jin-Guo
Min, An-Jie
Fu, Yao-Wen
author_sort Wang, Na
collection PubMed
description The title ion-pair compound, (C(7)H(7)N(2))(2)[Cu(C(4)N(2)S(2))(2)], was obtained by the direct reaction of CuCl(2)·2H(2)O, disodium maleonitrile­dithiol­ate (Na(2)mnt) and 4-cyano-1-methyl­pyridinium iodide. The anion and one pyridinium cation lie entirely on a mirror plane, whereas for the other cation, a crystallographic mirror plane runs through the N and para-C atoms of the pyridine ring, the methyl C atom, and the cyano group. In the crystal, ions are linked into a three-dimensional network by C—H⋯N hydrogen bonds.
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spelling pubmed-32748942012-02-15 Bis(4-cyano-1-methyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)cuprate(II) Wang, Na Wang, Jin-Guo Min, An-Jie Fu, Yao-Wen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title ion-pair compound, (C(7)H(7)N(2))(2)[Cu(C(4)N(2)S(2))(2)], was obtained by the direct reaction of CuCl(2)·2H(2)O, disodium maleonitrile­dithiol­ate (Na(2)mnt) and 4-cyano-1-methyl­pyridinium iodide. The anion and one pyridinium cation lie entirely on a mirror plane, whereas for the other cation, a crystallographic mirror plane runs through the N and para-C atoms of the pyridine ring, the methyl C atom, and the cyano group. In the crystal, ions are linked into a three-dimensional network by C—H⋯N hydrogen bonds. International Union of Crystallography 2012-01-18 /pmc/articles/PMC3274894/ /pubmed/22346841 http://dx.doi.org/10.1107/S1600536812001377 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Na
Wang, Jin-Guo
Min, An-Jie
Fu, Yao-Wen
Bis(4-cyano-1-methyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)cuprate(II)
title Bis(4-cyano-1-methyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)cuprate(II)
title_full Bis(4-cyano-1-methyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)cuprate(II)
title_fullStr Bis(4-cyano-1-methyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)cuprate(II)
title_full_unstemmed Bis(4-cyano-1-methyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)cuprate(II)
title_short Bis(4-cyano-1-methyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)cuprate(II)
title_sort bis(4-cyano-1-methyl­pyridinium) bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) s,s′)cuprate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274894/
https://www.ncbi.nlm.nih.gov/pubmed/22346841
http://dx.doi.org/10.1107/S1600536812001377
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AT minanjie bis4cyano1methylpyridiniumbis12dicyanoethene12dithiolatok2sscuprateii
AT fuyaowen bis4cyano1methylpyridiniumbis12dicyanoethene12dithiolatok2sscuprateii

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