catena-Poly[[(5-phenyl-2,2′-bipyridine-κ(2) N,N′)copper(I)]-μ-thio­cyanido-κ(2) N:S]

The title compound, [Cu(NCS)(C(16)H(12)N(2))](n), was synthesised under hydro­thermal conditions. The Cu(I) ion shows distorted tetra­hedral geometry being coordinated by two N atoms from a 5-phenyl-2,2′-bipyridine ligand and by the N and S atoms from two different thio­cyanate anions. The Cu(I) ion...

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Detalles Bibliográficos
Autores principales: Cui, Shuxin, Zuo, Minghui, Zhang, Jingping, Zhao, Yulong, Wang, Hui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274895/
https://www.ncbi.nlm.nih.gov/pubmed/22346842
http://dx.doi.org/10.1107/S1600536812000682
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author Cui, Shuxin
Zuo, Minghui
Zhang, Jingping
Zhao, Yulong
Wang, Hui
author_facet Cui, Shuxin
Zuo, Minghui
Zhang, Jingping
Zhao, Yulong
Wang, Hui
author_sort Cui, Shuxin
collection PubMed
description The title compound, [Cu(NCS)(C(16)H(12)N(2))](n), was synthesised under hydro­thermal conditions. The Cu(I) ion shows distorted tetra­hedral geometry being coordinated by two N atoms from a 5-phenyl-2,2′-bipyridine ligand and by the N and S atoms from two different thio­cyanate anions. The Cu(I) ions are bridged by thio­cyanide groups, forming a one-dimensional coordination polymer along the b axis. The crystal packing is through van der Waals contacts and C—H⋯π inter­actions.
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spelling pubmed-32748952012-02-15 catena-Poly[[(5-phenyl-2,2′-bipyridine-κ(2) N,N′)copper(I)]-μ-thio­cyanido-κ(2) N:S] Cui, Shuxin Zuo, Minghui Zhang, Jingping Zhao, Yulong Wang, Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(NCS)(C(16)H(12)N(2))](n), was synthesised under hydro­thermal conditions. The Cu(I) ion shows distorted tetra­hedral geometry being coordinated by two N atoms from a 5-phenyl-2,2′-bipyridine ligand and by the N and S atoms from two different thio­cyanate anions. The Cu(I) ions are bridged by thio­cyanide groups, forming a one-dimensional coordination polymer along the b axis. The crystal packing is through van der Waals contacts and C—H⋯π inter­actions. International Union of Crystallography 2012-01-18 /pmc/articles/PMC3274895/ /pubmed/22346842 http://dx.doi.org/10.1107/S1600536812000682 Text en © Cui et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cui, Shuxin
Zuo, Minghui
Zhang, Jingping
Zhao, Yulong
Wang, Hui
catena-Poly[[(5-phenyl-2,2′-bipyridine-κ(2) N,N′)copper(I)]-μ-thio­cyanido-κ(2) N:S]
title catena-Poly[[(5-phenyl-2,2′-bipyridine-κ(2) N,N′)copper(I)]-μ-thio­cyanido-κ(2) N:S]
title_full catena-Poly[[(5-phenyl-2,2′-bipyridine-κ(2) N,N′)copper(I)]-μ-thio­cyanido-κ(2) N:S]
title_fullStr catena-Poly[[(5-phenyl-2,2′-bipyridine-κ(2) N,N′)copper(I)]-μ-thio­cyanido-κ(2) N:S]
title_full_unstemmed catena-Poly[[(5-phenyl-2,2′-bipyridine-κ(2) N,N′)copper(I)]-μ-thio­cyanido-κ(2) N:S]
title_short catena-Poly[[(5-phenyl-2,2′-bipyridine-κ(2) N,N′)copper(I)]-μ-thio­cyanido-κ(2) N:S]
title_sort catena-poly[[(5-phenyl-2,2′-bipyridine-κ(2) n,n′)copper(i)]-μ-thio­cyanido-κ(2) n:s]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274895/
https://www.ncbi.nlm.nih.gov/pubmed/22346842
http://dx.doi.org/10.1107/S1600536812000682
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