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catena-Poly[[trimethyltin(IV)]-μ-1,2,3-benzotriazol-1-ido-κ(2) N (1):N (3)]
In the title coordination polymer, [Sn(CH(3))(3)(C(6)H(4)N(3))](n), the Sn(IV) atom is five-coordinated in a distorted trigonal–bipyramidal geometry with the methyl groups in equatorial positions and two N atoms of two symmetry-related benzotriazolide anions in axial positions. The anion bridges adj...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274898/ https://www.ncbi.nlm.nih.gov/pubmed/22346845 http://dx.doi.org/10.1107/S1600536811055176 |
| Sumario: | In the title coordination polymer, [Sn(CH(3))(3)(C(6)H(4)N(3))](n), the Sn(IV) atom is five-coordinated in a distorted trigonal–bipyramidal geometry with the methyl groups in equatorial positions and two N atoms of two symmetry-related benzotriazolide anions in axial positions. The anion bridges adjacent metal atoms, forming zigzag polymeric chains parallel to [011] and [0[Image: see text]1]. |
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