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catena-Poly[[[tetraaquaneodymium(III)]-di-μ-isonicotinato] chloride]
In the title complex, {[Nd(C(6)H(4)NO(2))(2)(H(2)O)(4)]Cl}(n), the Nd(III) cation is located on a twofold rotation axis and coordinated by four isonicotiniate anions and four water molecules in a distorted square-antiprismatic geometry. The carboxylate groups of the isonicotinate anions bridge th...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274899/ https://www.ncbi.nlm.nih.gov/pubmed/22346846 http://dx.doi.org/10.1107/S1600536811055619 |
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author | Xue, Jun-Hui Hua, Xiao-Hui Li, Chun-Ping Xu, Yi-Zhuang Wu, Jin-Guang |
author_facet | Xue, Jun-Hui Hua, Xiao-Hui Li, Chun-Ping Xu, Yi-Zhuang Wu, Jin-Guang |
author_sort | Xue, Jun-Hui |
collection | PubMed |
description | In the title complex, {[Nd(C(6)H(4)NO(2))(2)(H(2)O)(4)]Cl}(n), the Nd(III) cation is located on a twofold rotation axis and coordinated by four isonicotiniate anions and four water molecules in a distorted square-antiprismatic geometry. The carboxylate groups of the isonicotinate anions bridge the Nd(III) cations, forming polymeric chains running along the c axis. The Cl(−) anion is located on a twofold rotation axis and is linked to the polymeric chains via O—H⋯Cl hydrogen bonding. Intermolecular O—H⋯O and O—H⋯N hydrogen bonds are also present in the crystal structure. |
format | Online Article Text |
id | pubmed-3274899 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32748992012-02-15 catena-Poly[[[tetraaquaneodymium(III)]-di-μ-isonicotinato] chloride] Xue, Jun-Hui Hua, Xiao-Hui Li, Chun-Ping Xu, Yi-Zhuang Wu, Jin-Guang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Nd(C(6)H(4)NO(2))(2)(H(2)O)(4)]Cl}(n), the Nd(III) cation is located on a twofold rotation axis and coordinated by four isonicotiniate anions and four water molecules in a distorted square-antiprismatic geometry. The carboxylate groups of the isonicotinate anions bridge the Nd(III) cations, forming polymeric chains running along the c axis. The Cl(−) anion is located on a twofold rotation axis and is linked to the polymeric chains via O—H⋯Cl hydrogen bonding. Intermolecular O—H⋯O and O—H⋯N hydrogen bonds are also present in the crystal structure. International Union of Crystallography 2012-01-18 /pmc/articles/PMC3274899/ /pubmed/22346846 http://dx.doi.org/10.1107/S1600536811055619 Text en © Xue et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xue, Jun-Hui Hua, Xiao-Hui Li, Chun-Ping Xu, Yi-Zhuang Wu, Jin-Guang catena-Poly[[[tetraaquaneodymium(III)]-di-μ-isonicotinato] chloride] |
title |
catena-Poly[[[tetraaquaneodymium(III)]-di-μ-isonicotinato] chloride] |
title_full |
catena-Poly[[[tetraaquaneodymium(III)]-di-μ-isonicotinato] chloride] |
title_fullStr |
catena-Poly[[[tetraaquaneodymium(III)]-di-μ-isonicotinato] chloride] |
title_full_unstemmed |
catena-Poly[[[tetraaquaneodymium(III)]-di-μ-isonicotinato] chloride] |
title_short |
catena-Poly[[[tetraaquaneodymium(III)]-di-μ-isonicotinato] chloride] |
title_sort | catena-poly[[[tetraaquaneodymium(iii)]-di-μ-isonicotinato] chloride] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274899/ https://www.ncbi.nlm.nih.gov/pubmed/22346846 http://dx.doi.org/10.1107/S1600536811055619 |
work_keys_str_mv | AT xuejunhui catenapolytetraaquaneodymiumiiidimisonicotinatochloride AT huaxiaohui catenapolytetraaquaneodymiumiiidimisonicotinatochloride AT lichunping catenapolytetraaquaneodymiumiiidimisonicotinatochloride AT xuyizhuang catenapolytetraaquaneodymiumiiidimisonicotinatochloride AT wujinguang catenapolytetraaquaneodymiumiiidimisonicotinatochloride |