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catena-Poly[[[tetra­aqua­neodymium(III)]-di-μ-isonicotinato] chloride]

In the title complex, {[Nd(C(6)H(4)NO(2))(2)(H(2)O)(4)]Cl}(n), the Nd(III) cation is located on a twofold rotation axis and coordinated by four isonicotiniate anions and four water mol­ecules in a distorted square-anti­prismatic geometry. The carboxyl­ate groups of the isonicotinate anions bridge th...

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Autores principales: Xue, Jun-Hui, Hua, Xiao-Hui, Li, Chun-Ping, Xu, Yi-Zhuang, Wu, Jin-Guang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274899/
https://www.ncbi.nlm.nih.gov/pubmed/22346846
http://dx.doi.org/10.1107/S1600536811055619
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author Xue, Jun-Hui
Hua, Xiao-Hui
Li, Chun-Ping
Xu, Yi-Zhuang
Wu, Jin-Guang
author_facet Xue, Jun-Hui
Hua, Xiao-Hui
Li, Chun-Ping
Xu, Yi-Zhuang
Wu, Jin-Guang
author_sort Xue, Jun-Hui
collection PubMed
description In the title complex, {[Nd(C(6)H(4)NO(2))(2)(H(2)O)(4)]Cl}(n), the Nd(III) cation is located on a twofold rotation axis and coordinated by four isonicotiniate anions and four water mol­ecules in a distorted square-anti­prismatic geometry. The carboxyl­ate groups of the isonicotinate anions bridge the Nd(III) cations, forming polymeric chains running along the c axis. The Cl(−) anion is located on a twofold rotation axis and is linked to the polymeric chains via O—H⋯Cl hydrogen bonding. Inter­molecular O—H⋯O and O—H⋯N hydrogen bonds are also present in the crystal structure.
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spelling pubmed-32748992012-02-15 catena-Poly[[[tetra­aqua­neodymium(III)]-di-μ-isonicotinato] chloride] Xue, Jun-Hui Hua, Xiao-Hui Li, Chun-Ping Xu, Yi-Zhuang Wu, Jin-Guang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Nd(C(6)H(4)NO(2))(2)(H(2)O)(4)]Cl}(n), the Nd(III) cation is located on a twofold rotation axis and coordinated by four isonicotiniate anions and four water mol­ecules in a distorted square-anti­prismatic geometry. The carboxyl­ate groups of the isonicotinate anions bridge the Nd(III) cations, forming polymeric chains running along the c axis. The Cl(−) anion is located on a twofold rotation axis and is linked to the polymeric chains via O—H⋯Cl hydrogen bonding. Inter­molecular O—H⋯O and O—H⋯N hydrogen bonds are also present in the crystal structure. International Union of Crystallography 2012-01-18 /pmc/articles/PMC3274899/ /pubmed/22346846 http://dx.doi.org/10.1107/S1600536811055619 Text en © Xue et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xue, Jun-Hui
Hua, Xiao-Hui
Li, Chun-Ping
Xu, Yi-Zhuang
Wu, Jin-Guang
catena-Poly[[[tetra­aqua­neodymium(III)]-di-μ-isonicotinato] chloride]
title catena-Poly[[[tetra­aqua­neodymium(III)]-di-μ-isonicotinato] chloride]
title_full catena-Poly[[[tetra­aqua­neodymium(III)]-di-μ-isonicotinato] chloride]
title_fullStr catena-Poly[[[tetra­aqua­neodymium(III)]-di-μ-isonicotinato] chloride]
title_full_unstemmed catena-Poly[[[tetra­aqua­neodymium(III)]-di-μ-isonicotinato] chloride]
title_short catena-Poly[[[tetra­aqua­neodymium(III)]-di-μ-isonicotinato] chloride]
title_sort catena-poly[[[tetra­aqua­neodymium(iii)]-di-μ-isonicotinato] chloride]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274899/
https://www.ncbi.nlm.nih.gov/pubmed/22346846
http://dx.doi.org/10.1107/S1600536811055619
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